Solubility measurements of hydrogen in 1-butyl-3-methylimidazolium tetrafluoroborate and the effect of carbon dioxide and a selected catalyst on the hydrogen solubility in the ionic liquid Toussaint, V.; Kühne, E.; Shariati, A.; Peters, C.; The Journal of Chemical Thermodynamics 2013, 59, 239-242
- Journal: The Journal of Chemical Thermodynamics
- Sample Quantity(ies): Vapor pressure
- Methodology: ISOPVT
- Phase(s): Gas' Liquid
- Substances:
- hydrogen H2 (UFHFLCQGNIYNRP-UHFFFAOYSA-N) - Commercial source
- 1-butyl-3-methylimidazolium tetrafluoroborate C8H15BF4N2 (LSBXQLQATZTAPE-UHFFFAOYSA-N) - Commercial source
- rhodium(1+), [(1,2,5,6-.nu.)-1,5-cyclooctadiene][(2R,2'R,5R,5'R)-1,1'-(1,2-phenylene)bis[2,5-dimethylphospholane-kP]]-, tetrafluoroborate(1-) (1:1) C26H40BF4P2Rh (FKGVQOXVEDXEEW-UHFFFAOYSA-N) - Commercial source
Data
| T (K) | P (kPa) |
| 314.10 | 52300.0 |
| 356.98 | 43400.0 |
| 361.62 | 42900.0 |
| 365.85 | 42600.0 |
| 318.95 | 51000.0 |
| 323.76 | 49800.0 |
| 328.41 | 48700.0 |
| 333.44 | 47600.0 |
| 338.02 | 46500.0 |
| 342.85 | 45400.0 |
| 347.58 | 44500.0 |
| 353.07 | 43700.0 |
41481; hydrogen + 1-butyl-3-methylimidazolium tetrafluoroborate + rhodium(1+), [(1,2,5,6-.nu.)-1,5-cyclooctadiene][(2R,2'R,5R,5'R)-1,1'-(1,2-phenylene)bis[2,5-dimethylphospholane-kP]]-, tetrafluoroborate(1-) (1:1); 00009:02571:07518