The heat capacity and entropy of the lithium silicides Li17Si4 and Li16.42Si4 in the temperature range from (2 to 873) K Thomas, D.; Zeilinger, M.; Gruner, D.; Hüttl, R.; Seidel, J.; Wolter, A.U.; Fässler, T.F.; Mertens, F.; The Journal of Chemical Thermodynamics 2015, 85, 178-190
- Journal: The Journal of Chemical Thermodynamics
- Sample Quantity(ies): Molar heat capacity at constant pressure
- Methodology: relaxation calorimetry + DSC
- Phase(s): Crystal of intercomponent compound 1
- Substances:
Data
| T (K) | Cp (J mol-1 K-1) |
| 5 | 0.0184 |
| 50 | 2.41 |
| 60 | 3.63 |
| 70 | 5.02 |
| 80 | 6.43 |
| 90 | 7.82 |
| 100 | 9.14 |
| 110 | 10.39 |
| 120 | 11.56 |
| 130 | 12.64 |
| 140 | 13.65 |
| 10 | 0.0403 |
| 150 | 14.58 |
| 160 | 15.43 |
| 170 | 16.22 |
| 180 | 16.94 |
| 190 | 17.6 |
| 200 | 18.2 |
| 210 | 18.76 |
| 220 | 19.27 |
| 230 | 19.74 |
| 240 | 20.18 |
| 15 | 0.0895 |
| 250 | 20.59 |
| 260 | 20.98 |
| 270 | 21.36 |
| 280 | 21.72 |
| 290 | 22.08 |
| 298.15 | 22.38 |
| 300 | 22.58 |
| 320 | 23.07 |
| 340 | 23.51 |
| 360 | 23.91 |
| 20 | 0.184 |
| 380 | 24.29 |
| 400 | 24.63 |
| 420 | 24.96 |
| 440 | 25.28 |
| 460 | 25.6 |
| 480 | 25.91 |
| 500 | 26.22 |
| 520 | 26.54 |
| 540 | 26.88 |
| 560 | 27.23 |
| 25 | 0.347 |
| 580 | 27.6 |
| 600 | 28.0 |
| 620 | 28.43 |
| 640 | 28.9 |
| 660 | 29.4 |
| 680 | 29.94 |
| 700 | 30.53 |
| 720 | 31.18 |
| 740 | 31.88 |
| 760 | 32.63 |
| 30 | 0.596 |
| 780 | 33.45 |
| 800 | 34.34 |
| 35 | 0.934 |
| 40 | 1.35 |
| 45 | 1.85 |
43511; lithium + silicon; 05184:05804