The heat capacity and entropy of the lithium silicides Li17Si4 and Li16.42Si4 in the temperature range from (2 to 873) K Thomas, D.; Zeilinger, M.; Gruner, D.; Hüttl, R.; Seidel, J.; Wolter, A.U.; Fässler, T.F.; Mertens, F.; The Journal of Chemical Thermodynamics 2015, 85, 178-190
- Journal: The Journal of Chemical Thermodynamics
- Sample Quantity(ies): Molar heat capacity at constant pressure
- Methodology: relaxation calorimetry + DSC
- Phase(s): Crystal of intercomponent compound 2
- Substances:
Data
| T (K) | Cp (J mol-1 K-1) |
| 5 | 0.0056 |
| 50 | 2.61 |
| 60 | 3.81 |
| 70 | 5.21 |
| 80 | 6.65 |
| 90 | 8.08 |
| 100 | 9.44 |
| 110 | 10.73 |
| 120 | 11.93 |
| 130 | 13.04 |
| 140 | 14.07 |
| 10 | 0.0233 |
| 150 | 15.01 |
| 160 | 15.88 |
| 170 | 16.67 |
| 180 | 17.39 |
| 190 | 18.05 |
| 200 | 18.65 |
| 210 | 19.19 |
| 220 | 19.69 |
| 230 | 20.16 |
| 240 | 20.58 |
| 15 | 0.0803 |
| 250 | 20.99 |
| 260 | 21.37 |
| 270 | 21.73 |
| 280 | 22.09 |
| 290 | 22.45 |
| 298.15 | 22.75 |
| 300 | 22.79 |
| 320 | 23.22 |
| 340 | 23.65 |
| 360 | 24.08 |
| 20 | 0.201 |
| 380 | 24.51 |
| 400 | 24.94 |
| 420 | 25.37 |
| 440 | 25.8 |
| 460 | 26.23 |
| 480 | 26.66 |
| 500 | 27.09 |
| 520 | 27.52 |
| 540 | 27.95 |
| 560 | 28.38 |
| 25 | 0.403 |
| 580 | 28.81 |
| 600 | 29.25 |
| 620 | 29.68 |
| 640 | 30.11 |
| 660 | 30.54 |
| 680 | 30.97 |
| 700 | 31.4 |
| 720 | 31.84 |
| 740 | 32.3 |
| 760 | 32.82 |
| 30 | 0.689 |
| 780 | 33.49 |
| 800 | 34.61 |
| 820 | 36.83 |
| 840 | 41.72 |
| 860 | 52.81 |
| 35 | 1.056 |
| 40 | 1.5 |
| 45 | 2.01 |
43511; lithium + silicon; 05184:05804