The heat capacity and entropy of the lithium silicides Li17Si4 and Li16.42Si4 in the temperature range from (2 to 873) K Thomas, D.; Zeilinger, M.; Gruner, D.; Hüttl, R.; Seidel, J.; Wolter, A.U.; Fässler, T.F.; Mertens, F.; The Journal of Chemical Thermodynamics 2015, 85, 178-190
Data
P = 100 kPa, x = 0.810 mol mol-1
T (K) Cp (J mol-1 K-1)
2.03 0.0088
3.24 0.0133
192.69 17.73
196.78 17.96
200.80 18.22
204.92 18.43
208.93 18.63
213.05 18.87
217.11 19.04
221.12 19.24
225.24 19.46
229.30 19.66
3.41 0.0135
233.30 19.83
237.41 20.0
241.48 20.17
245.48 20.3
249.60 20.44
253.67 20.58
257.66 20.7
261.78 20.8
265.84 20.92
269.85 21.06
3.60 0.0141
273.90 21.15
278.02 21.25
282.08 21.37
286.08 21.42
290.12 21.52
294.26 21.6
298.32 21.66
302.31 21.75
3.79 0.015
3.99 0.0157
4.20 0.0163
4.43 0.0172
4.67 0.0175
4.92 0.0182
5.18 0.0193
2.13 0.0091
5.47 0.0201
5.76 0.0206
6.07 0.0218
6.39 0.0227
6.73 0.0242
7.09 0.0252
7.47 0.0267
7.87 0.0284
8.30 0.0304
8.74 0.0327
2.25 0.0096
9.20 0.0351
9.70 0.038
10.22 0.0412
10.75 0.0449
11.32 0.0492
11.93 0.0547
12.56 0.0613
13.23 0.0671
13.94 0.0741
14.69 0.083
2.37 0.0101
15.47 0.094
16.30 0.1071
17.17 0.1224
18.09 0.1403
19.06 0.1618
20.09 0.187
21.16 0.219
22.28 0.255
23.51 0.297
24.74 0.331
2.49 0.0107
26.08 0.39
27.48 0.457
28.95 0.534
30.49 0.625
32.12 0.728
33.84 0.848
35.66 0.987
37.56 1.143
39.56 1.315
41.67 1.513
2.63 0.0111
43.88 1.731
46.22 1.98
48.69 2.259
51.29 2.56
54.03 2.89
56.91 3.26
59.95 3.65
63.15 4.08
66.53 4.52
70.08 5.02
2.77 0.0116
73.83 5.54
77.77 6.09
81.93 6.66
86.31 7.27
90.93 7.89
91.01 7.88
95.01 8.41
99.07 8.94
103.16 9.52
107.24 10.04
2.92 0.0121
111.29 10.53
115.39 11.05
119.47 11.55
123.51 12.0
127.61 12.47
131.69 12.88
135.76 13.31
139.83 13.71
143.86 14.08
147.97 14.51
3.08 0.0126
152.00 14.84
156.10 15.17
160.12 15.52
164.23 15.85
168.29 16.17
172.36 16.41
176.43 16.71
180.45 16.95
184.57 17.2
188.59 17.45
43511; lithium + silicon; 05184:05804