The heat capacity and entropy of the lithium silicides Li17Si4 and Li16.42Si4 in the temperature range from (2 to 873) K Thomas, D.; Zeilinger, M.; Gruner, D.; Hüttl, R.; Seidel, J.; Wolter, A.U.; Fässler, T.F.; Mertens, F.; The Journal of Chemical Thermodynamics 2015, 85, 178-190
Data
P = 100 kPa, x = 0.804 mol mol-1
T (K) Cp (J mol-1 K-1)
2.03 0.0022
2.50 0.0025
26.07 0.454
27.47 0.534
27.48 0.531
28.94 0.623
28.95 0.619
30.48 0.723
30.50 0.718
32.11 0.835
32.12 0.832
33.83 0.964
2.63 0.0028
33.84 0.961
35.64 1.113
35.65 1.109
37.54 1.278
37.56 1.272
39.55 1.458
39.57 1.455
41.66 1.664
41.68 1.659
43.89 1.888
2.63 0.0025
43.90 1.888
46.23 2.145
46.23 2.142
48.70 2.429
48.72 2.429
51.30 2.74
51.30 2.74
54.03 3.08
54.04 3.08
56.92 3.45
2.77 0.0028
56.92 3.45
59.96 3.84
59.96 3.84
63.17 4.27
63.18 4.27
66.54 4.72
66.55 4.73
70.10 5.22
70.11 5.22
73.84 5.75
2.77 0.0028
73.86 5.75
77.78 6.31
77.80 6.32
81.94 6.9
81.95 6.9
86.32 7.53
86.33 7.53
90.93 8.14
90.95 8.17
91.00 8.16
2.92 0.0031
91.02 8.18
95.02 8.71
95.04 8.73
99.06 9.29
99.08 9.32
103.16 9.83
103.18 9.87
107.25 10.37
107.26 10.4
111.29 10.88
2.92 0.003
111.31 10.88
115.40 11.39
115.41 11.41
119.47 11.87
119.49 11.92
123.51 12.35
123.53 12.4
127.62 12.78
127.64 12.84
131.69 13.22
3.08 0.0032
131.71 13.3
135.76 13.64
135.78 13.71
139.83 14.04
139.85 14.09
143.87 14.45
143.88 14.5
147.98 14.83
147.99 14.94
152.00 15.17
3.08 0.003
152.02 15.29
156.10 15.54
156.12 15.62
160.13 15.86
160.14 15.96
164.23 16.22
164.24 16.27
168.29 16.53
168.31 16.6
172.36 16.79
3.24 0.0035
172.38 16.9
176.43 17.06
176.43 17.19
180.45 17.33
180.46 17.44
184.56 17.58
184.57 17.69
188.58 17.84
188.59 17.97
192.69 18.09
2.03 0.0022
3.24 0.0032
192.71 18.27
196.74 18.32
196.78 18.47
200.77 18.54
200.80 18.74
204.91 18.8
204.93 18.97
208.92 19.05
208.94 19.19
213.04 19.24
3.41 0.0036
213.05 19.41
217.10 19.42
217.12 19.59
221.11 19.62
221.13 19.84
225.23 19.86
225.25 20.03
229.28 20.05
229.31 20.22
233.29 20.23
3.41 0.0036
233.31 20.38
237.40 20.4
237.43 20.54
241.46 20.62
241.49 20.73
245.47 20.87
245.50 20.93
249.59 21.0
249.62 21.13
253.66 21.14
3.60 0.0039
253.68 21.27
257.65 21.3
257.68 21.42
261.78 21.42
261.79 21.54
265.83 21.55
265.86 21.64
269.82 21.67
269.85 21.75
273.88 21.84
3.60 0.0036
273.91 21.9
278.02 21.93
278.04 22.0
282.07 22.06
282.09 22.11
286.06 22.16
286.08 22.26
290.13 22.36
294.27 22.5
298.33 22.58
3.79 0.0041
302.34 22.69
3.79 0.004
3.99 0.0044
3.99 0.0042
4.20 0.0047
2.13 0.0023
4.20 0.0044
4.43 0.0048
4.43 0.005
4.66 0.0051
4.67 0.0052
4.91 0.0056
4.92 0.0054
5.18 0.006
5.18 0.0057
5.46 0.0064
2.14 0.0022
5.47 0.0061
5.76 0.007
5.76 0.0066
6.07 0.0075
6.07 0.0071
6.39 0.0083
6.39 0.0079
6.73 0.0091
6.73 0.0088
7.09 0.0098
2.25 0.0024
7.09 0.01
7.47 0.0113
7.47 0.0109
7.87 0.0126
7.87 0.0123
8.29 0.0143
8.29 0.0139
8.74 0.016
8.74 0.0162
9.20 0.0183
2.25 0.0023
9.20 0.0187
9.69 0.0216
9.69 0.0208
10.22 0.0245
10.22 0.025
10.75 0.0286
10.75 0.0291
11.32 0.0342
11.32 0.0335
11.93 0.0403
2.37 0.0024
11.93 0.0398
12.56 0.0482
12.56 0.0474
13.23 0.0553
13.24 0.0547
13.94 0.0639
13.95 0.0628
14.69 0.0753
14.69 0.0743
15.47 0.0889
2.37 0.0025
15.48 0.0879
16.30 0.1049
16.31 0.1039
17.18 0.1233
17.18 0.1231
18.09 0.1454
18.10 0.1461
19.07 0.1725
19.07 0.1731
20.09 0.205
2.49 0.0026
20.10 0.203
21.16 0.24
21.17 0.242
22.30 0.283
22.30 0.286
23.49 0.333
23.49 0.337
24.75 0.391
24.75 0.396
26.07 0.458
43511; lithium + silicon; 05184:05804