Calorimetric study of polymorphism in 1-butyl-3-methylimidazolium hexafluorophosphate Paulechka, E.; Liavitskaya, T.; Blokhin, A.V.; The Journal of Chemical Thermodynamics 2016, 102, 211-218
- Journal: The Journal of Chemical Thermodynamics
- Sample Quantity(ies): Molar heat capacity at constant pressure
- Methodology: Small (less than 1 g) adiabatic calorimetry
- Phase(s): Metastable crystal
- Substances:
Data
| T (K) | Cp (J mol-1 K-1) |
| 5.14 | 2.42 |
| 9.20 | 10.06 |
| 157.67 | 228.7 |
| 159.55 | 231.5 |
| 161.42 | 234.4 |
| 163.29 | 237.3 |
| 165.15 | 240.3 |
| 167.01 | 243.2 |
| 168.87 | 246.3 |
| 170.71 | 249.4 |
| 172.55 | 252.6 |
| 174.39 | 256.1 |
| 9.75 | 11.33 |
| 176.22 | 258.9 |
| 178.04 | 260.8 |
| 179.86 | 263.5 |
| 181.68 | 266.1 |
| 183.50 | 268.6 |
| 185.31 | 270.9 |
| 187.12 | 273.0 |
| 188.92 | 274.8 |
| 190.72 | 276.4 |
| 192.53 | 277.7 |
| 10.36 | 12.83 |
| 194.33 | 278.7 |
| 196.13 | 279.3 |
| 197.94 | 279.8 |
| 199.74 | 280.0 |
| 201.61 | 280.4 |
| 203.54 | 280.7 |
| 205.47 | 281.0 |
| 207.40 | 281.3 |
| 209.34 | 281.8 |
| 211.28 | 282.5 |
| 11.05 | 14.53 |
| 213.22 | 283.4 |
| 215.16 | 284.4 |
| 217.10 | 285.1 |
| 219.04 | 285.7 |
| 220.98 | 286.7 |
| 222.93 | 287.8 |
| 224.86 | 288.7 |
| 226.90 | 290.0 |
| 228.84 | 291.1 |
| 230.78 | 292.0 |
| 11.75 | 16.3 |
| 232.72 | 293.0 |
| 234.67 | 294.1 |
| 236.61 | 295.2 |
| 238.55 | 296.3 |
| 240.49 | 298.3 |
| 242.43 | 299.6 |
| 12.45 | 18.11 |
| 13.16 | 19.96 |
| 13.87 | 21.84 |
| 14.59 | 23.69 |
| 15.31 | 25.67 |
| 5.39 | 2.76 |
| 16.14 | 28.07 |
| 17.09 | 30.62 |
| 18.04 | 33.1 |
| 18.99 | 35.56 |
| 19.94 | 37.99 |
| 21.20 | 41.25 |
| 22.78 | 45.26 |
| 24.36 | 49.25 |
| 25.94 | 53.1 |
| 27.42 | 56.44 |
| 5.74 | 3.28 |
| 28.99 | 60.0 |
| 30.59 | 63.64 |
| 32.36 | 67.48 |
| 34.28 | 71.38 |
| 36.21 | 75.09 |
| 38.14 | 78.66 |
| 40.07 | 82.09 |
| 42.09 | 85.6 |
| 44.21 | 89.2 |
| 46.33 | 92.75 |
| 6.10 | 3.85 |
| 48.45 | 96.18 |
| 50.58 | 99.47 |
| 52.71 | 102.6 |
| 54.84 | 105.6 |
| 56.97 | 108.5 |
| 59.11 | 111.3 |
| 61.24 | 114.0 |
| 63.37 | 116.6 |
| 65.51 | 119.2 |
| 67.65 | 121.8 |
| 6.54 | 4.59 |
| 69.79 | 124.4 |
| 72.04 | 127.0 |
| 74.39 | 129.8 |
| 76.74 | 132.5 |
| 79.09 | 135.1 |
| 81.45 | 137.7 |
| 83.81 | 140.2 |
| 78.34 | 134.5 |
| 80.13 | 136.3 |
| 81.80 | 138.1 |
| 7.06 | 5.54 |
| 83.48 | 139.8 |
| 85.17 | 141.6 |
| 86.86 | 143.5 |
| 88.56 | 145.3 |
| 90.27 | 147.2 |
| 91.99 | 149.0 |
| 93.71 | 150.9 |
| 95.45 | 152.7 |
| 97.19 | 154.7 |
| 98.94 | 156.5 |
| 7.59 | 6.57 |
| 100.69 | 158.4 |
| 102.50 | 160.3 |
| 104.38 | 162.4 |
| 106.27 | 164.4 |
| 108.17 | 166.5 |
| 110.06 | 168.6 |
| 111.96 | 170.7 |
| 113.86 | 172.8 |
| 115.77 | 174.9 |
| 117.68 | 177.1 |
| 8.12 | 7.67 |
| 119.59 | 179.2 |
| 121.50 | 181.4 |
| 123.41 | 183.7 |
| 125.32 | 185.9 |
| 127.23 | 188.2 |
| 129.15 | 190.5 |
| 131.06 | 192.8 |
| 132.97 | 195.1 |
| 134.88 | 197.5 |
| 136.80 | 199.9 |
| 8.66 | 8.84 |
| 138.71 | 202.4 |
| 140.62 | 204.8 |
| 142.52 | 207.4 |
| 144.42 | 209.9 |
| 146.33 | 212.5 |
| 148.23 | 215.1 |
| 150.13 | 217.7 |
| 152.02 | 220.4 |
| 153.91 | 223.1 |
| 155.79 | 225.9 |
1383; 1-butyl-3-methylimidazolium hexafluorophosphate; 00481