Low-temperature heat capacity and thermodynamic functions of natural chalcanthite Bissengaliyeva, M.; Bekturganov, N.; Gogol, D.; Taimassova, S.; The Journal of Chemical Thermodynamics 2017, 111, 199-206
- Journal: The Journal of Chemical Thermodynamics
- Sample Quantity(ies): Molar heat capacity at constant pressure
- Methodology: Small (less than 1 g) adiabatic calorimetry
- Phase(s): Crystal
- Substances:
Data
| T (K) | Cp (J mol-1 K-1) |
| 4.3109 | 0.504615406 |
| 7.2490 | 0.613478502 |
| 35.636 | 30.1870374 |
| 37.610 | 33.5203455 |
| 22.857 | 11.971944328 |
| 23.863 | 13.21088626 |
| 24.838 | 14.417119326 |
| 25.814 | 15.699256936 |
| 26.794 | 16.966413386 |
| 27.772 | 18.33194612 |
| 28.749 | 19.727940546 |
| 29.726 | 21.15464635 |
| 7.7131 | 0.700119544 |
| 30.705 | 22.534910558 |
| 31.683 | 24.034274988 |
| 32.663 | 25.55785896 |
| 33.645 | 27.01103148 |
| 34.625 | 28.57406584 |
| 35.606 | 30.07218184 |
| 36.586 | 31.75506548 |
| 37.570 | 33.30311868 |
| 38.555 | 34.93356826 |
| 39.539 | 36.50659006 |
| 8.1817 | 0.78526247 |
| 25.494 | 15.24832402 |
| 26.504 | 16.5916347 |
| 27.479 | 17.90498306 |
| 28.455 | 19.31071524 |
| 29.434 | 20.68398824 |
| 30.412 | 22.10719844 |
| 31.391 | 23.59283014 |
| 32.369 | 25.13838648 |
| 33.355 | 26.55160924 |
| 34.338 | 28.09966244 |
| 8.6323 | 0.901116774 |
| 35.315 | 29.6502125 |
| 36.293 | 31.17829082 |
| 37.273 | 32.75380948 |
| 38.254 | 34.36678104 |
| 39.234 | 35.95228714 |
| 40.216 | 37.51032778 |
| 41.204 | 39.02342494 |
| 42.188 | 40.34676074 |
| 43.170 | 41.93226684 |
| 44.155 | 43.28806182 |
| 9.0901 | 1.042688736 |
| 45.139 | 44.6064039 |
| 46.125 | 45.8673182 |
| 47.111 | 47.23809434 |
| 48.097 | 48.61636106 |
| 49.083 | 50.17689856 |
| 50.070 | 52.0095938 |
| 51.056 | 53.88972938 |
| 52.043 | 55.62255022 |
| 53.029 | 57.23302492 |
| 54.016 | 58.81853102 |
| 9.5553 | 1.149054972 |
| 55.003 | 60.25921924 |
| 55.991 | 61.62749852 |
| 56.979 | 62.68866402 |
| 57.966 | 63.82473532 |
| 58.956 | 65.22797064 |
| 59.945 | 66.92084172 |
| 60.934 | 68.42395144 |
| 61.924 | 69.94453918 |
| 62.916 | 71.40020856 |
| 63.908 | 72.71106006 |
| 10.016 | 1.296869084 |
| 64.901 | 74.00443354 |
| 65.894 | 75.33775678 |
| 66.888 | 76.71352664 |
| 67.882 | 78.07431534 |
| 68.878 | 79.31026104 |
| 69.873 | 80.5362193 |
| 71.869 | 83.37514912 |
| 74.876 | 87.17537004 |
| 77.893 | 90.83077308 |
| 80.916 | 94.51613844 |
| 10.703 | 1.568777138 |
| 36.258 | 31.26318406 |
| 38.339 | 34.69636656 |
| 40.314 | 37.77249808 |
| 42.293 | 40.62640906 |
| 44.271 | 43.37545192 |
| 46.249 | 46.07705444 |
| 48.229 | 48.95343716 |
| 50.209 | 52.309217 |
| 52.192 | 55.66000312 |
| 54.176 | 58.7261472 |
| 11.618 | 1.98999742 |
| 56.162 | 61.64997026 |
| 58.150 | 64.4689252 |
| 60.141 | 67.29537072 |
| 62.134 | 70.09185392 |
| 64.128 | 72.85338108 |
| 66.123 | 75.64986428 |
| 68.091 | 78.22412694 |
| 70.002 | 80.85332052 |
| 72.446 | 84.21159722 |
| 75.455 | 87.9768621 |
| 12.542 | 2.453414636 |
| 78.476 | 91.70717094 |
| 81.507 | 95.35758026 |
| 79.111 | 92.2090398 |
| 82.478 | 96.20151894 |
| 85.520 | 99.6871355 |
| 88.568 | 103.18523636 |
| 91.620 | 106.68084036 |
| 94.679 | 110.0865574 |
| 97.743 | 113.4073812 |
| 100.82 | 116.61834316 |
| 4.5393 | 0.517349392 |
| 13.466 | 3.010214416 |
| 103.89 | 120.07649426 |
| 106.97 | 123.24251274 |
| 110.06 | 126.4160218 |
| 113.16 | 129.60201516 |
| 116.25 | 132.90286408 |
| 119.36 | 135.8791212 |
| 122.46 | 138.97023388 |
| 125.57 | 142.11128376 |
| 128.70 | 145.1549561 |
| 131.82 | 148.19613158 |
| 14.393 | 3.629685382 |
| 134.93 | 151.22731962 |
| 138.05 | 154.26350138 |
| 141.16 | 157.4519916 |
| 144.28 | 160.35084606 |
| 147.40 | 163.32460632 |
| 150.52 | 166.25591996 |
| 153.64 | 169.31457346 |
| 156.76 | 172.31829604 |
| 159.88 | 175.23462852 |
| 163.01 | 178.3756784 |
| 15.326 | 4.330054612 |
| 166.13 | 181.26204856 |
| 169.26 | 184.17588418 |
| 172.38 | 187.03478888 |
| 175.51 | 189.77634116 |
| 178.63 | 192.28069174 |
| 181.75 | 194.98728798 |
| 184.87 | 197.90861418 |
| 187.99 | 200.27064374 |
| 191.11 | 202.9073279 |
| 194.23 | 206.13826474 |
| 16.265 | 5.102083724 |
| 197.34 | 208.76745832 |
| 200.44 | 211.49402944 |
| 203.52 | 214.1556822 |
| 206.59 | 216.64255476 |
| 209.64 | 219.17686766 |
| 212.68 | 221.85100472 |
| 215.69 | 224.42526738 |
| 218.69 | 227.07443584 |
| 221.67 | 229.64620164 |
| 224.64 | 232.1330742 |
| 17.211 | 5.919555688 |
| 227.61 | 234.56002212 |
| 230.54 | 237.24414662 |
| 233.45 | 239.84337788 |
| 236.34 | 241.9956712 |
| 239.22 | 244.57742444 |
| 242.10 | 246.15044624 |
| 244.96 | 248.55492242 |
| 247.81 | 250.7721341 |
| 250.65 | 253.28647212 |
| 253.49 | 254.98933064 |
| 18.161 | 6.787963596 |
| 256.31 | 256.80954158 |
| 259.10 | 259.74584894 |
| 261.91 | 260.8219956 |
| 264.69 | 262.84195534 |
| 267.47 | 265.71833806 |
| 270.26 | 267.95552462 |
| 273.15 | 269.83066648 |
| 275.93 | 272.17771488 |
| 278.71 | 274.33250506 |
| 281.48 | 276.4648235 |
| 19.116 | 7.73776914 |
| 284.24 | 278.43484604 |
| 287.00 | 280.48227124 |
| 289.76 | 282.27501672 |
| 292.51 | 284.1176994 |
| 295.26 | 285.99783498 |
| 298.02 | 287.87797056 |
| 300.77 | 289.97533296 |
| 303.53 | 291.76807844 |
| 306.28 | 293.5932831 |
| 309.04 | 295.49838728 |
| 20.074 | 8.711294854 |
| 311.80 | 297.26117044 |
| 314.56 | 298.99399128 |
| 317.53 | 300.51707588 |
| 320.30 | 302.56450108 |
| 323.07 | 304.16998206 |
| 86.118 | 100.39624374 |
| 87.258 | 101.63218944 |
| 88.283 | 102.82818538 |
| 89.308 | 103.95926296 |
| 90.333 | 105.21268668 |
| 21.516 | 10.37070801 |
| 91.362 | 106.31879566 |
| 92.392 | 107.489823 |
| 93.424 | 108.58594454 |
| 94.457 | 109.82189024 |
| 95.492 | 110.96545212 |
| 96.528 | 111.90427148 |
| 97.565 | 113.09777056 |
| 98.603 | 114.41111892 |
| 99.649 | 115.37241002 |
| 100.69 | 116.48600958 |
| 23.438 | 12.670815442 |
| 101.73 | 117.58712484 |
| 102.79 | 118.7007244 |
| 103.84 | 119.78436164 |
| 104.89 | 120.90295492 |
| 105.93 | 122.01405762 |
| 106.98 | 123.13764462 |
| 108.03 | 124.24625046 |
| 109.08 | 125.36484374 |
| 110.13 | 126.45846842 |
| 111.18 | 127.43723754 |
| 4.8226 | 0.492880164 |
| 4.3049 | 0.548310456 |
| 112.23 | 128.51837792 |
| 113.29 | 129.53959366 |
| 114.34 | 130.68065868 |
| 115.39 | 131.77678022 |
| 116.44 | 132.81048026 |
| 117.50 | 133.8441803 |
| 118.55 | 134.96027672 |
| 119.63 | 136.13879464 |
| 120.69 | 136.93529298 |
| 121.74 | 138.14627008 |
| 4.5235 | 0.519596566 |
| 122.80 | 139.1749764 |
| 123.86 | 140.25861364 |
| 124.91 | 141.44462214 |
| 125.97 | 142.62563692 |
| 127.03 | 143.4570913 |
| 128.08 | 144.35096718 |
| 129.14 | 145.37467978 |
| 130.20 | 146.58066316 |
| 131.25 | 147.54944484 |
| 132.31 | 148.61061034 |
| 4.7982 | 0.498373256 |
| 133.37 | 149.93144928 |
| 134.43 | 150.80035656 |
| 135.49 | 151.95390588 |
| 136.56 | 152.70046702 |
| 137.61 | 153.74914822 |
| 138.67 | 154.90269754 |
| 139.72 | 155.89644782 |
| 140.78 | 156.9401353 |
| 141.83 | 157.84399862 |
| 142.89 | 158.79030856 |
| 5.0688 | 0.496375768 |
| 143.94 | 159.81901488 |
| 144.99 | 160.85021806 |
| 146.04 | 161.99377994 |
| 147.09 | 162.84021548 |
| 148.14 | 163.74158194 |
| 149.18 | 164.71286048 |
| 150.23 | 165.79899458 |
| 151.27 | 167.02245598 |
| 152.32 | 167.82145118 |
| 153.38 | 169.0249377 |
| 5.3424 | 0.494627966 |
| 154.42 | 169.98373194 |
| 155.47 | 171.06736918 |
| 156.52 | 172.02616342 |
| 157.57 | 172.98495766 |
| 158.61 | 173.87633668 |
| 159.66 | 174.8176529 |
| 160.71 | 175.82388748 |
| 161.75 | 176.91002158 |
| 162.80 | 177.97368394 |
| 163.85 | 178.90251586 |
| 5.6207 | 0.49687514 |
| 164.89 | 179.87629126 |
| 165.94 | 180.89501014 |
| 166.99 | 181.71897394 |
| 168.03 | 182.65529644 |
| 169.08 | 183.63656242 |
| 170.13 | 184.5554069 |
| 171.17 | 185.59410066 |
| 89.573 | 104.25139558 |
| 91.841 | 106.74575872 |
| 93.888 | 109.01790132 |
| 5.9002 | 0.511107242 |
| 95.935 | 111.25259102 |
| 97.982 | 113.44233724 |
| 100.03 | 115.64956148 |
| 102.08 | 117.97164128 |
| 104.14 | 120.09397228 |
| 106.20 | 122.39358034 |
| 108.27 | 124.44100554 |
| 110.33 | 126.53836794 |
| 112.40 | 128.69565498 |
| 114.47 | 130.81299226 |
| 6.2909 | 0.524839972 |
| 116.54 | 133.17502182 |
| 118.62 | 135.00022648 |
| 120.69 | 137.14253236 |
| 122.80 | 139.2623665 |
| 124.88 | 141.31228856 |
| 126.97 | 143.35971376 |
| 129.05 | 145.43710128 |
| 131.13 | 147.52447624 |
| 133.22 | 149.56690772 |
| 135.30 | 151.52694282 |
| 6.7781 | 0.558547582 |
| 137.39 | 153.54939942 |
| 139.47 | 155.52691254 |
| 141.56 | 157.54687228 |
| 143.64 | 159.59679434 |
| 145.73 | 161.62674152 |
| 147.81 | 163.57429232 |
| 149.89 | 165.55929602 |
| 151.97 | 167.62919296 |
| 154.06 | 169.63417154 |
| 156.15 | 171.6840936 |
| 7.2541 | 0.6117307 |
| 158.24 | 173.61666324 |
| 160.32 | 175.82638434 |
| 162.41 | 177.56170204 |
| 164.49 | 179.68902676 |
| 166.58 | 181.29950146 |
| 168.67 | 183.22208366 |
| 170.76 | 185.14716272 |
| 172.85 | 187.25700942 |
| 174.95 | 188.9373962 |
| 177.04 | 190.61278926 |
| 5.1041 | 0.49437828 |
| 7.7228 | 0.693877394 |
| 179.13 | 192.37307556 |
| 181.21 | 194.29066404 |
| 183.30 | 195.97105082 |
| 185.39 | 197.77378374 |
| 187.48 | 199.99099542 |
| 189.57 | 201.44416794 |
| 191.66 | 203.2069511 |
| 193.74 | 205.3043135 |
| 195.83 | 207.12452444 |
| 197.92 | 209.0121506 |
| 8.1891 | 0.786011528 |
| 200.02 | 210.2855492 |
| 202.12 | 212.11075386 |
| 204.22 | 214.40037448 |
| 206.33 | 215.54893008 |
| 208.45 | 218.00833718 |
| 210.58 | 219.17936452 |
| 212.70 | 220.96711628 |
| 214.83 | 222.90218278 |
| 216.96 | 224.83225556 |
| 219.10 | 226.57506384 |
| 8.6534 | 0.893376508 |
| 221.23 | 229.06693012 |
| 223.42 | 230.1480705 |
| 225.57 | 231.88588506 |
| 227.72 | 233.68861798 |
| 229.87 | 235.53629438 |
| 232.02 | 238.2753498 |
| 234.17 | 240.04312668 |
| 236.33 | 241.78593496 |
| 238.49 | 242.57244586 |
| 240.64 | 245.25157664 |
| 9.1163 | 1.028206948 |
| 242.81 | 246.88452308 |
| 244.99 | 248.4750229 |
| 247.17 | 250.060529 |
| 249.35 | 251.8332996 |
| 251.54 | 253.6060702 |
| 253.73 | 255.6035582 |
| 255.93 | 257.4012974 |
| 258.20 | 258.7745704 |
| 260.42 | 260.5972782 |
| 262.65 | 262.419986 |
| 9.5830 | 1.165284562 |
| 264.88 | 264.1178508 |
| 267.12 | 265.8406842 |
| 269.37 | 267.5135804 |
| 271.62 | 269.2364138 |
| 273.88 | 270.90931 |
| 276.14 | 271.783211 |
| 278.38 | 274.5547256 |
| 280.66 | 275.029129 |
| 282.91 | 276.6271194 |
| 285.16 | 279.2987596 |
| 10.050 | 1.31459679 |
| 287.46 | 280.8218442 |
| 289.76 | 282.2450544 |
| 292.07 | 282.8692694 |
| 294.48 | 285.7905956 |
| 296.84 | 287.3636174 |
| 299.23 | 288.761859 |
| 301.59 | 289.4859484 |
| 303.92 | 292.0577142 |
| 306.30 | 293.9303592 |
| 308.68 | 295.753067 |
| 10.765 | 1.599987888 |
| 311.08 | 296.127596 |
| 313.44 | 298.7992362 |
| 315.85 | 300.247415 |
| 318.28 | 301.4708764 |
| 320.71 | 302.8191808 |
| 323.15 | 304.367234 |
| 11.695 | 2.014216962 |
| 12.621 | 2.500105918 |
| 13.550 | 3.048416374 |
| 5.3778 | 0.492880164 |
| 14.482 | 3.676126978 |
| 4.2613 | 0.51560159 |
| 4.3954 | 0.5368249 |
| 4.5826 | 0.524090914 |
| 4.7773 | 0.49687514 |
| 4.9778 | 0.502867604 |
| 5.1770 | 0.489634246 |
| 5.3719 | 0.488885188 |
| 5.5600 | 0.493878908 |
| 5.7486 | 0.49063299 |
| 5.6506 | 0.49687514 |
| 5.9374 | 0.498872628 |
| 6.1721 | 0.50186886 |
| 6.4477 | 0.535826156 |
| 6.7263 | 0.555301664 |
| 7.0015 | 0.58551367 |
| 7.2732 | 0.628209976 |
| 7.5473 | 0.663415702 |
| 7.8235 | 0.71659882 |
| 8.0957 | 0.778770634 |
| 8.3710 | 0.847434284 |
| 5.9253 | 0.501619174 |
| 8.6502 | 0.90136646 |
| 8.9279 | 0.968032622 |
| 9.2035 | 1.056920838 |
| 9.4805 | 1.13357444 |
| 9.7562 | 1.19974123 |
| 10.032 | 1.306107466 |
| 10.399 | 1.456418438 |
| 10.859 | 1.633695498 |
| 11.317 | 1.834942414 |
| 11.777 | 2.059410128 |
| 6.3028 | 0.518597822 |
| 12.239 | 2.282629412 |
| 12.698 | 2.532814784 |
| 13.159 | 2.801227234 |
| 13.622 | 3.098852946 |
| 14.087 | 3.403719552 |
| 14.551 | 3.735052874 |
| 14.236 | 3.509586416 |
| 15.329 | 4.31582251 |
| 16.339 | 5.147027204 |
| 17.344 | 6.038156538 |
| 6.7744 | 0.566537534 |
| 18.344 | 6.974479038 |
| 19.340 | 7.949752554 |
| 20.335 | 8.968221748 |
| 21.842 | 10.734999884 |
| 23.798 | 13.116255266 |
| 25.753 | 15.842327014 |
| 27.719 | 18.238813242 |
| 29.695 | 21.255519494 |
| 31.682 | 23.15463121 |
| 33.665 | 26.86121988 |
46200; copper(II) sulfate pentahydrate; 07972