Thermodynamic and X-ray studies of layered perovskite KCa2NaNb4O13 Knyazev, A.; Krasheninnikova, O.; Syrov, E.; Kyashkin, V.; Lelet, M.; Smirnova, N.; The Journal of Chemical Thermodynamics 2019, 138, 255-261
- Journal: The Journal of Chemical Thermodynamics
- Sample Quantity(ies): Molar heat capacity at constant pressure
- Methodology: Vacuum adiabatic calorimetry
- Phase(s): Crystal 2
- Substances:
Data
| T (K) | Cp (J mol-1 K-1) |
| 6.81 | 0.0288 |
| 8.39 | 0.0375 |
| 178.95 | 317.7 |
| 182.29 | 321.8 |
| 185.61 | 325.5 |
| 188.95 | 329.9 |
| 192.21 | 333.4 |
| 195.45 | 336.7 |
| 198.66 | 340.1 |
| 201.85 | 343.6 |
| 205.02 | 346.9 |
| 208.18 | 349.9 |
| 8.59 | 0.0399 |
| 211.32 | 352.9 |
| 214.45 | 355.8 |
| 217.56 | 358.8 |
| 220.66 | 361.9 |
| 223.76 | 364.6 |
| 226.83 | 367.9 |
| 229.80 | 370.1 |
| 232.94 | 373.5 |
| 235.98 | 376.8 |
| 239.13 | 379.5 |
| 8.80 | 0.0451 |
| 242.16 | 382.1 |
| 245.17 | 383.9 |
| 248.19 | 386.1 |
| 251.20 | 388.4 |
| 254.21 | 390.7 |
| 257.22 | 393.5 |
| 260.22 | 395.8 |
| 263.21 | 398.2 |
| 266.21 | 400.3 |
| 269.20 | 402.6 |
| 9.01 | 0.0522 |
| 272.18 | 404.3 |
| 275.17 | 407.1 |
| 278.15 | 408.5 |
| 281.13 | 410.8 |
| 284.11 | 412.5 |
| 287.27 | 414.5 |
| 290.25 | 416.1 |
| 293.22 | 417.6 |
| 296.19 | 420.1 |
| 299.15 | 422.2 |
| 9.24 | 0.0637 |
| 303.48 | 424.3 |
| 308.78 | 427.0 |
| 314.04 | 429.7 |
| 319.26 | 432.2 |
| 324.44 | 434.7 |
| 329.58 | 436.8 |
| 334.65 | 439.1 |
| 339.66 | 441.0 |
| 344.59 | 442.5 |
| 9.46 | 0.0801 |
| 9.69 | 0.116 |
| 9.93 | 0.142 |
| 10.40 | 0.226 |
| 10.83 | 0.34 |
| 6.96 | 0.0292 |
| 11.37 | 0.53 |
| 11.92 | 0.79 |
| 12.47 | 1.09 |
| 13.02 | 1.4 |
| 13.59 | 1.74 |
| 14.17 | 2.08 |
| 14.75 | 2.451 |
| 15.32 | 2.808 |
| 15.90 | 3.231 |
| 16.48 | 3.717 |
| 7.12 | 0.0295 |
| 17.06 | 4.131 |
| 17.64 | 4.684 |
| 18.23 | 5.176 |
| 18.82 | 5.843 |
| 19.20 | 6.301 |
| 19.80 | 7.046 |
| 21.35 | 9.197 |
| 23.77 | 12.76 |
| 26.80 | 17.03 |
| 29.39 | 21.5 |
| 7.29 | 0.0301 |
| 32.04 | 26.61 |
| 34.75 | 32.03 |
| 37.50 | 37.86 |
| 40.29 | 43.66 |
| 43.12 | 49.53 |
| 45.97 | 55.92 |
| 48.85 | 63.32 |
| 51.75 | 70.56 |
| 55.73 | 81.74 |
| 59.07 | 89.87 |
| 7.46 | 0.0308 |
| 62.03 | 97.33 |
| 65.01 | 104.9 |
| 68.00 | 112.7 |
| 71.00 | 120.5 |
| 74.25 | 128.8 |
| 77.76 | 136.4 |
| 81.28 | 145.2 |
| 84.80 | 155.4 |
| 88.34 | 164.5 |
| 91.89 | 172.5 |
| 7.64 | 0.0316 |
| 95.44 | 180.6 |
| 99.01 | 188.3 |
| 102.83 | 196.0 |
| 106.89 | 204.4 |
| 111.01 | 212.8 |
| 115.08 | 221.0 |
| 115.13 | 221.1 |
| 117.29 | 223.1 |
| 120.78 | 230.2 |
| 124.25 | 236.6 |
| 7.82 | 0.0325 |
| 127.98 | 242.6 |
| 131.02 | 247.4 |
| 134.51 | 252.8 |
| 138.21 | 258.6 |
| 141.71 | 264.5 |
| 145.01 | 269.7 |
| 148.65 | 275.7 |
| 152.21 | 280.8 |
| 155.42 | 285.7 |
| 159.02 | 291.2 |
| 8.00 | 0.034 |
| 162.54 | 296.6 |
| 166.21 | 301.8 |
| 169.84 | 306.0 |
| 173.12 | 309.6 |
| 176.71 | 313.6 |
| 180.21 | 316.8 |
| 127.62 | 240.9 |
| 131.66 | 248.2 |
| 135.65 | 255.1 |
| 139.55 | 260.8 |
| 8.20 | 0.0354 |
| 143.39 | 267.1 |
| 147.16 | 273.2 |
| 150.87 | 279.0 |
| 154.53 | 284.4 |
| 158.14 | 289.8 |
| 161.71 | 295.0 |
| 165.23 | 300.0 |
| 168.71 | 304.6 |
| 172.16 | 309.2 |
| 175.57 | 313.7 |
48377; calcium niobium potassium sodium oxide (Ca2Nb4KNaO13); 08477