An experimental calorimetric and a DFT + U study of the thermodynamic properties of Cs4UO24WO5W2O8O2 and Cs4[UO27WO53O3] Lelet, M.I.; Yakun'kova, M.L.; Kowalski, P.M.; Suleimanov, E.V.; Geiger, C.A.; Alekseev, E.V.; The Journal of Chemical Thermodynamics 2019, 139, 105873
- Journal: The Journal of Chemical Thermodynamics
- Sample Quantity(ies): Molar heat capacity at constant pressure
- Methodology: Vacuum adiabatic calorimetry
- Phase(s): Crystal
- Substances:
Data
| T (K) | Cp (J mol-1 K-1) |
| 5 | 1.98 |
| 50 | 208.5 |
| 60 | 248.1 |
| 70 | 284.5 |
| 80 | 318.1 |
| 90 | 348.0 |
| 100 | 375.6 |
| 110 | 401.9 |
| 120 | 426.8 |
| 130 | 450.3 |
| 140 | 472.2 |
| 10 | 13.6 |
| 150 | 492.5 |
| 160 | 511.3 |
| 170 | 528.8 |
| 180 | 545.1 |
| 190 | 560.4 |
| 200 | 574.8 |
| 210 | 588.6 |
| 220 | 601.7 |
| 230 | 614.3 |
| 240 | 626.5 |
| 15 | 35.9 |
| 250 | 638.2 |
| 260 | 649.5 |
| 270 | 660.5 |
| 273.15 | 663.8 |
| 280 | 671.0 |
| 290 | 681.0 |
| 298.15 | 688.8 |
| 300 | 690.5 |
| 310 | 699.3 |
| 320 | 707.5 |
| 20 | 64.4 |
| 25 | 95.1 |
| 30 | 121.7 |
| 35 | 145.1 |
| 40 | 166.9 |
| 45 | 187.9 |
48402; cesium tungsten uranium oxide (Cs4W3U4O23); 08481