An experimental calorimetric and a DFT + U study of the thermodynamic properties of Cs4UO24WO5W2O8O2 and Cs4[UO27WO53O3] Lelet, M.I.; Yakun'kova, M.L.; Kowalski, P.M.; Suleimanov, E.V.; Geiger, C.A.; Alekseev, E.V.; The Journal of Chemical Thermodynamics 2019, 139, 105873
Data
P = 101.325 kPa
T (K) Cp (J mol-1 K-1)
5.51 2.54
6.62 4.38
60.52 249.2
61.74 253.9
62.96 259.0
64.18 263.6
65.41 268.8
66.63 273.3
67.85 277.8
69.08 281.6
70.31 285.1
71.93 291.0
6.72 4.5
73.57 297.2
74.57 300.2
76.45 305.5
78.81 313.5
81.16 321.6
83.17 328.4
85.17 334.8
87.18 339.7
89.18 345.9
91.18 352.2
6.81 4.72
93.18 357.7
95.17 363.0
99.17 372.1
102.02 380.2
104.99 387.6
107.98 395.2
110.97 403.8
113.97 412.3
116.97 420.4
119.98 427.3
6.91 4.91
122.99 434.6
126.01 440.5
129.03 447.9
132.06 454.5
135.08 462.2
138.11 469.6
141.15 475.1
144.19 481.1
147.26 487.2
150.31 493.3
7.02 5.03
153.35 498.9
156.40 504.2
159.46 510.3
162.51 515.8
165.57 521.4
168.62 525.4
171.68 532.2
174.74 537.1
177.81 542.2
180.87 546.4
7.13 5.29
183.94 551.0
187.00 555.3
190.07 559.9
193.14 565.0
196.26 569.1
199.33 574.1
202.41 577.4
205.49 581.0
209.06 587.2
213.16 592.4
7.23 5.48
217.26 597.7
221.36 603.3
225.46 608.7
229.56 613.8
233.66 619.4
237.77 624.2
241.87 630.4
245.98 634.2
250.08 638.7
254.19 643.7
7.29 5.6
258.37 648.6
262.47 652.7
266.57 656.5
270.68 662.1
274.78 665.6
278.88 669.2
282.98 673.2
287.08 676.3
291.17 680.3
295.25 684.9
7.40 5.85
299.33 690.0
304.12 695.9
310.17 700.4
316.90 704.9
323.60 710.5
7.52 6.11
5.75 2.86
7.63 6.45
7.74 6.72
7.86 7.02
7.98 7.34
8.10 7.67
8.23 7.97
8.35 8.38
8.48 8.74
8.62 9.15
8.75 9.44
5.85 3.06
8.89 9.82
9.02 10.15
9.16 10.56
9.26 10.81
9.40 11.33
9.54 11.93
9.69 12.44
9.83 13.0
9.98 13.52
10.22 14.37
6.01 3.29
10.53 15.6
10.85 16.89
11.17 18.16
11.50 19.69
11.84 21.15
12.19 22.64
12.54 24.15
12.90 26.05
13.27 27.73
13.62 29.2
6.15 3.51
14.00 30.77
14.37 32.66
14.76 34.61
15.15 36.54
15.54 38.53
15.93 40.73
16.33 42.86
16.73 45.13
17.14 47.47
17.55 50.06
6.24 3.66
17.96 52.23
18.38 54.54
18.80 57.35
19.22 60.01
19.64 62.44
20.07 64.94
20.82 69.26
21.88 75.83
22.96 82.96
23.84 88.48
6.33 3.85
24.93 94.96
26.04 100.6
27.16 106.9
28.28 112.7
29.42 118.7
30.55 124.6
31.70 130.3
32.85 135.5
34.00 140.4
35.16 146.0
6.42 4.04
36.32 150.8
37.49 156.8
38.66 161.7
39.84 166.2
41.02 170.8
42.23 175.9
43.42 180.1
44.61 185.1
45.80 190.6
47.00 196.1
6.52 4.17
48.19 202.0
49.39 207.2
50.59 211.8
51.69 215.8
53.08 222.3
54.44 227.1
55.65 231.3
56.87 234.7
58.08 239.9
59.30 245.0
48402; cesium tungsten uranium oxide (Cs4W3U4O23); 08481