An experimental calorimetric and a DFT + U study of the thermodynamic properties of Cs4UO24WO5W2O8O2 and Cs4[UO27WO53O3] Lelet, M.I.; Yakun'kova, M.L.; Kowalski, P.M.; Suleimanov, E.V.; Geiger, C.A.; Alekseev, E.V.; The Journal of Chemical Thermodynamics 2019, 139, 105873
Data
P = 101.325 kPa
T (K) Cp (J mol-1 K-1)
4.81 3.69
6.05 7.45
75.71 397.4
77.73 408.0
78.87 413.1
81.28 425.8
83.28 437.3
85.29 445.9
87.29 454.3
89.29 462.8
91.29 471.6
93.29 480.8
6.25 8.15
95.29 490.0
97.28 498.8
99.27 505.3
101.75 515.9
104.73 526.7
107.72 536.6
110.72 547.2
113.71 558.6
116.73 565.9
119.74 575.6
6.42 8.8
122.75 586.5
125.76 596.5
128.78 606.1
131.80 615.9
134.82 624.5
137.85 634.2
140.88 643.3
143.91 651.6
146.94 660.7
149.98 669.7
6.61 9.48
153.02 678.2
156.06 686.2
159.11 694.4
162.16 702.9
165.24 711.9
168.28 720.3
171.33 728.7
174.38 737.4
177.43 744.7
180.48 752.6
6.79 10.17
183.53 761.6
186.58 768.2
189.63 775.4
192.68 781.9
195.74 789.1
198.79 796.3
201.84 801.2
204.89 806.3
208.44 813.8
212.50 820.3
6.98 10.88
216.61 828.9
220.67 834.8
224.73 840.9
228.78 850.8
232.83 857.5
236.88 862.9
240.94 870.5
244.98 874.1
249.03 879.4
253.06 885.4
7.17 11.59
257.09 892.8
261.12 898.2
265.14 903.2
269.15 907.8
273.16 914.0
277.16 919.6
281.14 926.7
285.12 931.9
289.09 935.4
293.04 941.1
7.35 12.28
296.98 946.5
300.91 951.6
305.42 957.5
310.46 965.8
315.14 972.8
319.92 980.2
324.69 987.7
7.54 12.98
7.73 13.84
4.90 3.99
7.92 14.58
8.12 15.68
8.31 16.59
8.52 17.23
8.72 18.09
8.92 19.22
9.13 20.0
9.33 21.11
9.54 22.13
9.75 23.28
5.03 4.3
9.97 24.41
10.27 25.75
10.66 27.67
11.05 29.84
11.44 32.33
11.84 34.41
12.24 36.62
12.65 39.02
13.05 41.0
13.46 43.47
5.11 4.5
13.88 45.66
14.29 48.26
14.70 50.53
15.12 52.99
15.53 55.68
15.95 58.27
16.37 60.83
16.79 63.55
17.21 66.32
17.63 69.42
5.23 4.83
18.05 72.24
18.47 75.31
18.90 78.25
19.32 81.28
19.75 83.97
20.17 87.58
20.92 93.24
21.98 100.9
23.05 108.4
24.14 115.8
5.36 5.22
25.23 123.1
26.34 129.8
27.45 137.3
28.57 145.2
29.70 152.7
30.83 160.4
31.74 167.1
32.97 175.3
34.12 182.9
35.28 189.2
5.51 5.67
36.44 195.7
37.60 201.8
38.77 208.3
39.94 214.7
41.12 220.7
42.31 228.6
44.03 238.8
45.38 246.1
46.58 253.1
47.78 260.7
5.68 6.19
48.98 267.1
50.18 272.9
51.39 277.8
52.59 283.5
53.80 289.9
55.01 294.9
56.22 301.3
57.43 306.1
58.65 313.4
59.86 319.9
5.86 6.78
61.08 326.5
62.30 334.3
63.55 340.0
64.92 347.8
66.37 355.9
67.59 362.1
68.82 367.4
70.05 373.6
71.67 380.1
73.69 388.1
48403; cesium tungsten uranium oxide (Cs4W3U7O32); 08482