Thermodynamic properties of BaCeO3 and BaZrO3 at low temperatures Ahrens, M.; Maier, J.; Thermochimica Acta 2006, 443, 189-196
- Journal: Thermochimica Acta
- Sample Quantity(ies): Molar heat capacity at constant pressure
- Methodology: Small (less than 1 g) adiabatic calorimetry
- Phase(s): Crystal
- Substances:
Data
| T (K) | Cp (J mol-1 K-1) |
| 1.659 | 0.00346 |
| 1.699 | 0.00335 |
| 9.33 | 0.13 |
| 9.47 | 0.148 |
| 9.60 | 0.144 |
| 9.75 | 0.163 |
| 9.88 | 0.159 |
| 10.01 | 0.17 |
| 10.18 | 0.188 |
| 10.31 | 0.186 |
| 10.47 | 0.208 |
| 10.60 | 0.205 |
| 1.722 | 0.00326 |
| 10.76 | 0.228 |
| 10.94 | 0.235 |
| 11.09 | 0.245 |
| 11.27 | 0.27 |
| 11.45 | 0.278 |
| 11.62 | 0.29 |
| 11.80 | 0.317 |
| 12.00 | 0.341 |
| 12.15 | 0.34 |
| 12.35 | 0.385 |
| 1.735 | 0.00341 |
| 12.54 | 0.383 |
| 12.72 | 0.416 |
| 12.92 | 0.449 |
| 13.12 | 0.466 |
| 13.32 | 0.5 |
| 13.53 | 0.54 |
| 13.73 | 0.561 |
| 13.93 | 0.599 |
| 14.13 | 0.628 |
| 14.34 | 0.692 |
| 1.744 | 0.00345 |
| 14.54 | 0.702 |
| 14.75 | 0.772 |
| 14.97 | 0.803 |
| 15.18 | 0.858 |
| 15.39 | 0.892 |
| 15.59 | 0.951 |
| 15.81 | 1.02 |
| 16.03 | 1.06 |
| 16.24 | 1.13 |
| 16.46 | 1.2 |
| 1.763 | 0.00333 |
| 16.68 | 1.25 |
| 16.90 | 1.32 |
| 17.12 | 1.4 |
| 17.34 | 1.46 |
| 17.56 | 1.54 |
| 17.79 | 1.63 |
| 18.03 | 1.72 |
| 18.26 | 1.77 |
| 18.47 | 1.87 |
| 18.69 | 1.97 |
| 2.098 | 0.00292 |
| 18.92 | 2.07 |
| 19.15 | 2.15 |
| 19.38 | 2.27 |
| 19.62 | 2.37 |
| 19.86 | 2.44 |
| 20.07 | 2.59 |
| 20.32 | 2.69 |
| 20.56 | 2.75 |
| 20.77 | 2.91 |
| 21.00 | 3.03 |
| 2.107 | 0.00345 |
| 21.25 | 3.1 |
| 21.47 | 3.28 |
| 21.71 | 3.37 |
| 21.95 | 3.48 |
| 22.17 | 3.66 |
| 22.41 | 3.78 |
| 22.67 | 3.87 |
| 22.90 | 3.98 |
| 23.11 | 4.17 |
| 23.34 | 4.32 |
| 2.124 | 0.00373 |
| 23.59 | 4.41 |
| 23.83 | 4.56 |
| 24.06 | 4.76 |
| 24.31 | 4.87 |
| 24.56 | 4.97 |
| 24.78 | 5.12 |
| 25.00 | 5.34 |
| 25.24 | 5.49 |
| 25.50 | 5.6 |
| 25.74 | 5.74 |
| 2.150 | 0.0036 |
| 25.96 | 5.93 |
| 26.19 | 6.12 |
| 26.44 | 6.29 |
| 26.70 | 6.36 |
| 26.94 | 6.51 |
| 27.15 | 6.76 |
| 27.39 | 6.91 |
| 27.68 | 6.91 |
| 27.72 | 7.04 |
| 28.07 | 7.4 |
| 2.163 | 0.00346 |
| 28.32 | 7.57 |
| 28.59 | 7.63 |
| 28.82 | 7.79 |
| 29.03 | 8.03 |
| 29.26 | 8.25 |
| 30.07 | 8.73 |
| 30.34 | 8.73 |
| 30.45 | 8.93 |
| 31.03 | 9.36 |
| 31.64 | 9.8 |
| 1.662 | 0.00357 |
| 2.173 | 0.00343 |
| 32.28 | 10.4 |
| 32.94 | 10.9 |
| 33.63 | 11.4 |
| 34.33 | 11.9 |
| 35.05 | 12.4 |
| 35.78 | 13.0 |
| 36.53 | 13.5 |
| 37.28 | 14.1 |
| 38.03 | 14.7 |
| 38.80 | 15.3 |
| 2.185 | 0.00389 |
| 39.58 | 15.9 |
| 40.37 | 16.4 |
| 41.18 | 17.1 |
| 42.00 | 17.7 |
| 42.84 | 18.3 |
| 43.69 | 19.0 |
| 44.56 | 19.6 |
| 45.45 | 20.2 |
| 46.36 | 21.0 |
| 47.29 | 21.6 |
| 2.198 | 0.00355 |
| 48.24 | 22.3 |
| 49.21 | 23.0 |
| 50.25 | 23.7 |
| 51.26 | 24.4 |
| 52.27 | 25.2 |
| 53.27 | 25.9 |
| 54.27 | 26.6 |
| 55.27 | 27.3 |
| 56.27 | 28.1 |
| 57.27 | 28.8 |
| 2.209 | 0.00288 |
| 58.26 | 29.5 |
| 59.25 | 30.2 |
| 60.25 | 31.0 |
| 61.24 | 31.6 |
| 62.30 | 32.5 |
| 63.25 | 33.2 |
| 64.23 | 33.8 |
| 65.21 | 34.5 |
| 66.20 | 35.2 |
| 67.19 | 35.9 |
| 2.216 | 0.00344 |
| 68.19 | 36.2 |
| 69.19 | 36.9 |
| 71.18 | 38.3 |
| 72.18 | 38.8 |
| 73.19 | 39.5 |
| 74.19 | 40.0 |
| 75.18 | 40.7 |
| 76.18 | 41.3 |
| 77.18 | 42.0 |
| 78.18 | 42.5 |
| 2.228 | 0.00346 |
| 79.18 | 43.1 |
| 80.18 | 43.6 |
| 81.18 | 44.3 |
| 82.18 | 44.7 |
| 83.18 | 45.1 |
| 84.17 | 45.7 |
| 85.17 | 46.3 |
| 86.17 | 46.7 |
| 87.17 | 47.2 |
| 87.74 | 46.8 |
| 2.261 | 0.00391 |
| 89.50 | 48.5 |
| 91.29 | 49.3 |
| 93.12 | 50.1 |
| 94.99 | 51.3 |
| 96.90 | 52.1 |
| 98.84 | 52.7 |
| 100.82 | 53.7 |
| 102.81 | 54.6 |
| 104.80 | 55.6 |
| 106.79 | 56.6 |
| 2.281 | 0.0035 |
| 108.78 | 57.5 |
| 110.77 | 58.4 |
| 112.76 | 59.4 |
| 114.75 | 60.3 |
| 116.74 | 61.2 |
| 118.72 | 62.0 |
| 120.69 | 62.8 |
| 122.66 | 63.7 |
| 124.65 | 64.5 |
| 126.64 | 65.3 |
| 2.325 | 0.00371 |
| 128.63 | 66.1 |
| 130.62 | 66.8 |
| 132.27 | 67.5 |
| 133.60 | 68.0 |
| 134.94 | 68.5 |
| 136.28 | 69.0 |
| 137.64 | 69.5 |
| 139.02 | 70.0 |
| 140.41 | 70.1 |
| 141.81 | 70.6 |
| 2.372 | 0.0038 |
| 143.23 | 71.1 |
| 144.66 | 71.7 |
| 146.11 | 72.2 |
| 147.57 | 72.7 |
| 149.04 | 73.2 |
| 150.53 | 73.9 |
| 152.03 | 74.3 |
| 153.55 | 74.9 |
| 155.09 | 75.3 |
| 156.64 | 75.9 |
| 1.664 | 0.00348 |
| 2.389 | 0.00365 |
| 158.20 | 76.3 |
| 159.79 | 76.9 |
| 161.38 | 77.3 |
| 163.00 | 77.9 |
| 164.63 | 78.4 |
| 166.26 | 78.9 |
| 167.93 | 79.4 |
| 169.61 | 79.9 |
| 171.30 | 80.4 |
| 173.01 | 81.0 |
| 2.420 | 0.00384 |
| 174.74 | 81.4 |
| 176.49 | 82.0 |
| 178.25 | 82.3 |
| 180.03 | 83.0 |
| 181.83 | 83.5 |
| 183.65 | 84.1 |
| 185.48 | 84.7 |
| 187.34 | 85.1 |
| 189.21 | 85.5 |
| 191.10 | 86.2 |
| 2.515 | 0.00414 |
| 193.00 | 86.7 |
| 194.93 | 87.0 |
| 196.88 | 87.9 |
| 198.84 | 88.0 |
| 200.83 | 88.7 |
| 202.81 | 89.0 |
| 204.80 | 89.7 |
| 206.78 | 90.5 |
| 208.76 | 90.8 |
| 210.75 | 91.3 |
| 2.651 | 0.00484 |
| 212.73 | 92.4 |
| 214.71 | 91.7 |
| 216.70 | 92.1 |
| 218.69 | 92.5 |
| 220.66 | 93.0 |
| 222.65 | 93.4 |
| 224.62 | 94.0 |
| 226.60 | 94.3 |
| 228.58 | 94.9 |
| 230.56 | 95.7 |
| 2.824 | 0.00516 |
| 232.54 | 95.8 |
| 234.52 | 95.9 |
| 236.49 | 96.5 |
| 238.47 | 96.6 |
| 240.44 | 97.1 |
| 242.41 | 97.6 |
| 244.39 | 97.6 |
| 246.36 | 98.4 |
| 248.33 | 98.2 |
| 250.31 | 98.9 |
| 2.831 | 0.00564 |
| 252.27 | 99.4 |
| 254.25 | 99.7 |
| 256.22 | 99.7 |
| 258.19 | 99.8 |
| 260.16 | 100.3 |
| 262.12 | 100.7 |
| 264.08 | 100.7 |
| 266.04 | 101.8 |
| 268.01 | 102.2 |
| 269.99 | 101.6 |
| 2.919 | 0.00559 |
| 271.94 | 102.6 |
| 273.90 | 103.0 |
| 275.86 | 103.2 |
| 277.83 | 103.3 |
| 279.79 | 103.8 |
| 281.74 | 104.6 |
| 283.71 | 105.2 |
| 285.68 | 105.0 |
| 287.63 | 105.0 |
| 289.59 | 105.2 |
| 2.952 | 0.00633 |
| 291.54 | 107.0 |
| 293.51 | 106.2 |
| 295.49 | 107.4 |
| 297.42 | 106.6 |
| 299.39 | 106.6 |
| 301.32 | 107.9 |
| 3.106 | 0.00618 |
| 3.116 | 0.00718 |
| 1.666 | 0.00351 |
| 3.242 | 0.00714 |
| 3.366 | 0.00794 |
| 3.538 | 0.00865 |
| 3.656 | 0.00903 |
| 3.873 | 0.00964 |
| 3.987 | 0.0104 |
| 4.096 | 0.0108 |
| 4.199 | 0.0112 |
| 4.473 | 0.0129 |
| 4.617 | 0.0156 |
| 1.671 | 0.00353 |
| 4.702 | 0.0156 |
| 4.777 | 0.0158 |
| 4.851 | 0.0176 |
| 4.929 | 0.0183 |
| 5.008 | 0.02 |
| 5.086 | 0.019 |
| 5.165 | 0.021 |
| 5.246 | 0.0226 |
| 5.329 | 0.0234 |
| 5.410 | 0.0243 |
| 1.675 | 0.00351 |
| 5.489 | 0.0216 |
| 5.545 | 0.0289 |
| 5.640 | 0.0269 |
| 5.717 | 0.0288 |
| 5.79 | 0.0301 |
| 5.87 | 0.0306 |
| 5.93 | 0.0325 |
| 6.02 | 0.0336 |
| 6.08 | 0.0338 |
| 6.19 | 0.0357 |
| 1.677 | 0.00363 |
| 6.27 | 0.0366 |
| 6.36 | 0.0388 |
| 6.45 | 0.0407 |
| 6.54 | 0.0424 |
| 6.62 | 0.044 |
| 6.72 | 0.0458 |
| 6.80 | 0.0494 |
| 6.90 | 0.0501 |
| 6.98 | 0.0511 |
| 7.08 | 0.0539 |
| 1.683 | 0.00349 |
| 7.16 | 0.0547 |
| 7.26 | 0.0547 |
| 7.36 | 0.0593 |
| 7.47 | 0.0629 |
| 7.56 | 0.0638 |
| 7.67 | 0.0662 |
| 7.77 | 0.07 |
| 7.89 | 0.0767 |
| 7.98 | 0.076 |
| 8.10 | 0.0841 |
| 1.689 | 0.00342 |
| 8.20 | 0.083 |
| 8.32 | 0.091 |
| 8.43 | 0.0913 |
| 8.55 | 0.101 |
| 8.67 | 0.102 |
| 8.80 | 0.112 |
| 8.91 | 0.111 |
| 9.05 | 0.127 |
| 9.12 | 0.121 |
| 9.26 | 0.138 |
27414; barium zirconium(IV) oxide; 05329