Thermodynamic properties of BaCeO3 and BaZrO3 at low temperatures Ahrens, M.; Maier, J.; Thermochimica Acta 2006, 443, 189-196
- Journal: Thermochimica Acta
- Sample Quantity(ies): Molar heat capacity at constant pressure
- Methodology: Small (less than 1 g) adiabatic calorimetry
- Phase(s): Crystal
- Substances:
Data
| T (K) | Cp (J mol-1 K-1) |
| 1.721 | 0.00113 |
| 2.042 | 0.00152 |
| 12.72 | 0.859 |
| 12.93 | 0.919 |
| 13.15 | 0.983 |
| 13.37 | 1.05 |
| 13.59 | 1.12 |
| 13.82 | 1.2 |
| 14.05 | 1.28 |
| 14.28 | 1.36 |
| 14.51 | 1.45 |
| 14.74 | 1.54 |
| 2.096 | 0.00138 |
| 14.97 | 1.63 |
| 15.21 | 1.73 |
| 15.44 | 1.83 |
| 15.68 | 1.93 |
| 15.91 | 2.05 |
| 16.15 | 2.16 |
| 16.38 | 2.26 |
| 16.60 | 2.38 |
| 16.84 | 2.51 |
| 17.09 | 2.62 |
| 2.134 | 0.00153 |
| 17.32 | 2.75 |
| 17.55 | 2.89 |
| 17.79 | 3.02 |
| 18.03 | 3.16 |
| 18.27 | 3.3 |
| 18.52 | 3.44 |
| 18.76 | 3.58 |
| 19.00 | 3.73 |
| 19.23 | 3.89 |
| 19.47 | 4.05 |
| 2.178 | 0.0019 |
| 19.73 | 4.19 |
| 19.98 | 4.35 |
| 20.20 | 4.52 |
| 20.44 | 4.68 |
| 20.69 | 4.84 |
| 20.94 | 5.0 |
| 21.17 | 5.2 |
| 21.41 | 5.36 |
| 21.66 | 5.54 |
| 21.91 | 5.7 |
| 2.817 | 0.00505 |
| 22.16 | 5.88 |
| 22.39 | 6.07 |
| 22.63 | 6.26 |
| 22.88 | 6.44 |
| 23.14 | 6.62 |
| 23.38 | 6.81 |
| 23.62 | 7.0 |
| 23.86 | 7.2 |
| 24.10 | 7.39 |
| 24.36 | 7.58 |
| 2.844 | 0.00578 |
| 24.61 | 7.76 |
| 24.86 | 7.96 |
| 25.10 | 8.19 |
| 25.34 | 8.4 |
| 25.60 | 8.57 |
| 25.86 | 8.77 |
| 26.10 | 8.98 |
| 26.34 | 9.19 |
| 26.57 | 9.41 |
| 26.83 | 9.6 |
| 2.877 | 0.0056 |
| 27.09 | 9.8 |
| 27.35 | 9.96 |
| 27.60 | 10.2 |
| 27.83 | 10.4 |
| 28.07 | 10.7 |
| 28.33 | 10.8 |
| 28.59 | 10.7 |
| 28.92 | 11.3 |
| 29.29 | 11.6 |
| 29.83 | 12.1 |
| 3.154 | 0.00691 |
| 30.39 | 12.6 |
| 30.99 | 13.1 |
| 31.60 | 13.6 |
| 32.23 | 14.1 |
| 32.89 | 14.7 |
| 33.56 | 15.3 |
| 34.26 | 15.9 |
| 34.97 | 16.5 |
| 35.70 | 17.1 |
| 36.44 | 17.8 |
| 3.175 | 0.00697 |
| 37.19 | 18.4 |
| 37.95 | 19.1 |
| 38.72 | 19.8 |
| 39.50 | 20.4 |
| 40.30 | 21.1 |
| 41.10 | 21.8 |
| 41.92 | 22.5 |
| 42.76 | 23.2 |
| 43.61 | 24.0 |
| 44.48 | 24.7 |
| 3.250 | 0.00798 |
| 45.36 | 25.5 |
| 46.27 | 26.2 |
| 47.24 | 26.9 |
| 48.19 | 27.7 |
| 49.16 | 28.5 |
| 50.15 | 29.4 |
| 51.15 | 30.2 |
| 52.16 | 31.0 |
| 53.16 | 31.8 |
| 54.16 | 32.6 |
| 1.726 | 0.00106 |
| 3.258 | 0.00871 |
| 55.16 | 33.5 |
| 56.16 | 34.3 |
| 57.16 | 35.1 |
| 58.15 | 35.9 |
| 59.14 | 36.7 |
| 60.13 | 37.4 |
| 61.12 | 38.2 |
| 62.11 | 39.0 |
| 63.10 | 39.7 |
| 64.09 | 40.5 |
| 3.318 | 0.00829 |
| 65.08 | 41.3 |
| 66.07 | 42.0 |
| 67.07 | 42.8 |
| 68.06 | 43.6 |
| 69.05 | 44.3 |
| 70.05 | 45.0 |
| 71.04 | 45.8 |
| 72.03 | 46.6 |
| 73.03 | 47.3 |
| 74.02 | 47.8 |
| 3.349 | 0.00913 |
| 75.02 | 48.6 |
| 76.02 | 49.2 |
| 77.02 | 49.9 |
| 78.02 | 50.6 |
| 79.01 | 50.7 |
| 80.01 | 51.5 |
| 80.29 | 51.0 |
| 81.69 | 51.5 |
| 82.49 | 52.0 |
| 83.31 | 52.5 |
| 3.382 | 0.00944 |
| 84.14 | 53.1 |
| 84.98 | 53.7 |
| 85.82 | 54.2 |
| 86.68 | 54.7 |
| 87.55 | 55.3 |
| 88.43 | 55.8 |
| 89.31 | 56.3 |
| 90.21 | 56.9 |
| 91.11 | 57.4 |
| 92.02 | 58.0 |
| 3.471 | 0.0093 |
| 92.94 | 58.5 |
| 93.87 | 59.1 |
| 94.81 | 59.7 |
| 95.75 | 60.2 |
| 96.71 | 60.8 |
| 97.68 | 61.3 |
| 98.65 | 61.9 |
| 99.64 | 62.4 |
| 100.64 | 63.0 |
| 101.64 | 63.6 |
| 3.570 | 0.01 |
| 102.66 | 64.1 |
| 103.69 | 64.7 |
| 104.72 | 65.2 |
| 105.77 | 65.8 |
| 106.83 | 66.4 |
| 107.90 | 66.9 |
| 108.97 | 67.4 |
| 110.06 | 67.7 |
| 111.16 | 68.5 |
| 112.27 | 69.1 |
| 3.673 | 0.0107 |
| 113.40 | 69.7 |
| 114.53 | 70.2 |
| 115.68 | 70.8 |
| 116.83 | 71.4 |
| 118.00 | 71.9 |
| 119.18 | 72.4 |
| 120.37 | 73.0 |
| 121.58 | 73.5 |
| 122.79 | 74.0 |
| 124.02 | 74.6 |
| 3.834 | 0.0118 |
| 125.26 | 75.1 |
| 126.51 | 75.7 |
| 127.77 | 76.2 |
| 129.05 | 76.8 |
| 130.34 | 77.3 |
| 131.64 | 77.9 |
| 132.96 | 78.4 |
| 134.29 | 78.9 |
| 135.63 | 79.4 |
| 136.99 | 79.9 |
| 3.983 | 0.0132 |
| 138.36 | 80.4 |
| 139.74 | 80.9 |
| 141.54 | 81.6 |
| 142.95 | 82.2 |
| 144.38 | 82.8 |
| 145.83 | 83.2 |
| 147.28 | 83.8 |
| 148.76 | 84.5 |
| 150.25 | 85.0 |
| 151.75 | 85.6 |
| 4.140 | 0.0143 |
| 153.27 | 86.1 |
| 154.80 | 86.6 |
| 156.34 | 87.3 |
| 157.91 | 87.8 |
| 159.49 | 88.2 |
| 161.08 | 88.9 |
| 162.69 | 89.3 |
| 164.32 | 89.9 |
| 165.96 | 90.3 |
| 167.62 | 90.8 |
| 1.733 | 0.00113 |
| 4.241 | 0.0157 |
| 169.30 | 91.2 |
| 170.99 | 91.8 |
| 172.70 | 92.4 |
| 174.43 | 92.9 |
| 176.17 | 93.5 |
| 177.93 | 94.0 |
| 179.71 | 94.3 |
| 181.50 | 95.2 |
| 183.31 | 95.3 |
| 185.15 | 95.9 |
| 4.384 | 0.0171 |
| 187.00 | 96.4 |
| 188.86 | 97.1 |
| 190.75 | 97.8 |
| 192.65 | 98.0 |
| 194.58 | 98.2 |
| 196.52 | 98.2 |
| 198.48 | 98.6 |
| 200.46 | 99.2 |
| 202.45 | 99.5 |
| 204.43 | 100.0 |
| 4.454 | 0.0187 |
| 206.42 | 101.0 |
| 208.40 | 101.1 |
| 210.39 | 101.6 |
| 212.37 | 101.7 |
| 214.35 | 102.5 |
| 216.33 | 102.8 |
| 218.31 | 103.5 |
| 220.30 | 103.8 |
| 222.28 | 103.6 |
| 224.26 | 104.2 |
| 4.608 | 0.0193 |
| 226.23 | 105.1 |
| 228.22 | 105.0 |
| 230.20 | 105.5 |
| 232.17 | 106.2 |
| 234.15 | 106.2 |
| 236.14 | 106.1 |
| 238.10 | 106.8 |
| 240.08 | 106.6 |
| 242.05 | 107.3 |
| 244.02 | 107.1 |
| 4.680 | 0.0211 |
| 245.99 | 107.7 |
| 249.95 | 108.3 |
| 251.89 | 108.9 |
| 253.89 | 109.5 |
| 255.86 | 109.5 |
| 257.84 | 109.2 |
| 259.80 | 110.2 |
| 261.77 | 109.7 |
| 263.74 | 110.1 |
| 267.67 | 111.0 |
| 4.756 | 0.0223 |
| 269.63 | 110.4 |
| 271.61 | 110.6 |
| 273.57 | 111.4 |
| 275.53 | 111.7 |
| 277.50 | 111.9 |
| 279.46 | 112.8 |
| 281.42 | 112.8 |
| 283.39 | 112.0 |
| 285.35 | 114.0 |
| 287.30 | 114.2 |
| 4.835 | 0.0232 |
| 289.27 | 113.1 |
| 291.22 | 113.8 |
| 293.17 | 114.3 |
| 294.05 | 113.5 |
| 297.48 | 114.1 |
| 299.16 | 114.5 |
| 4.911 | 0.0245 |
| 4.992 | 0.026 |
| 5.071 | 0.0274 |
| 1.761 | 0.00102 |
| 5.152 | 0.0284 |
| 5.227 | 0.0294 |
| 5.296 | 0.0316 |
| 5.375 | 0.0321 |
| 5.441 | 0.0353 |
| 5.536 | 0.0361 |
| 5.614 | 0.0388 |
| 5.697 | 0.0405 |
| 5.780 | 0.0425 |
| 5.861 | 0.0448 |
| 1.781 | 0.00108 |
| 5.946 | 0.0466 |
| 6.034 | 0.0491 |
| 6.119 | 0.0516 |
| 6.209 | 0.0536 |
| 6.297 | 0.0571 |
| 6.366 | 0.057 |
| 6.457 | 0.0616 |
| 6.548 | 0.0639 |
| 6.647 | 0.0675 |
| 6.739 | 0.0705 |
| 1.833 | 0.00116 |
| 6.841 | 0.0743 |
| 6.930 | 0.0778 |
| 7.04 | 0.0831 |
| 7.13 | 0.0857 |
| 7.24 | 0.0907 |
| 7.34 | 0.0935 |
| 7.45 | 0.0993 |
| 7.55 | 0.103 |
| 7.66 | 0.11 |
| 7.76 | 0.115 |
| 1.870 | 0.00103 |
| 7.89 | 0.123 |
| 8.00 | 0.129 |
| 8.13 | 0.138 |
| 8.25 | 0.145 |
| 8.38 | 0.156 |
| 8.50 | 0.164 |
| 8.64 | 0.176 |
| 8.77 | 0.185 |
| 8.91 | 0.201 |
| 9.04 | 0.209 |
| 1.904 | 0.00103 |
| 9.17 | 0.221 |
| 9.32 | 0.241 |
| 9.46 | 0.251 |
| 9.59 | 0.266 |
| 9.75 | 0.289 |
| 9.92 | 0.309 |
| 10.08 | 0.328 |
| 10.23 | 0.348 |
| 10.40 | 0.377 |
| 10.58 | 0.4 |
| 1.995 | 0.00167 |
| 10.76 | 0.433 |
| 10.94 | 0.461 |
| 11.10 | 0.489 |
| 11.30 | 0.534 |
| 11.48 | 0.561 |
| 11.68 | 0.61 |
| 11.89 | 0.651 |
| 12.09 | 0.7 |
| 12.29 | 0.744 |
| 12.50 | 0.806 |
27415; barium cerium(IV) oxide; 05330