Thermodynamic properties of tetrabridged binuclear copper complexes with apical substituted pyridine ligands Dobrokhotova, Z.; Fomina, I.; Gavrichev, K.; Tyurin, A.; Ryumin, M.; Bykov, M.; Emelina, A.; Kiskin, M.; Fazylbekov, M.; Eremenko, I.; Thermochimica Acta 2010, 509, 67-72
- Journal: Thermochimica Acta
- Sample Quantity(ies): Molar enthalpy
- Methodology: Small (less than 1 g) adiabatic calorimetry
- Phase(s): Crystal 2
- Substances:
Data
| T (K) | Hm (kJ mol-1) |
| 10 | 0.0 |
| 60 | 7.156 |
| 70 | 9.875 |
| 80 | 12.98 |
| 90 | 16.48 |
| 100 | 20.35 |
| 110 | 24.59 |
| 120 | 29.17 |
| 130 | 34.07 |
| 140 | 39.26 |
| 150 | 44.74 |
| 15 | 0.18 |
| 160 | 50.49 |
| 170 | 56.49 |
| 180 | 62.73 |
| 190 | 69.2 |
| 200 | 75.9 |
| 210 | 82.82 |
| 220 | 89.95 |
| 230 | 97.29 |
| 240 | 104.8 |
| 250 | 112.6 |
| 20 | 0.486 |
| 260 | 120.5 |
| 270 | 128.5 |
| 25 | 0.909 |
| 30 | 1.453 |
| 35 | 2.122 |
| 40 | 2.912 |
| 45 | 3.817 |
| 50 | 4.829 |
27946; dicopper tetrapivalate, bis-2-aminopyridine complex; 05487