NIST TRC ThermoML Dataset

Thermodynamics of ketone + amine mixtures. Part X. Excess molar enthalpies at 298.15 K for N,N,N-triethylamine + 2-alkanone systems. Characterization of tertiary amine + 2-alkanone, and of amino-ketone + n-alkane mixtures in terms of DISQUAC González, J.A.; Alonso, I.; De La Fuente, I.G.; Cobos, J.C.; Fluid Phase Equilibria 2013, 356, 117-125

Journal: Fluid Phase Equilibria
Sample Quantity(ies): Excess molar enthalpy
Methodology: Calvet calorimetry
Phase(s): Liquid
Substances:
1. propyl methyl ketone C5H10O (XNLICIUVMPYHGG-UHFFFAOYSA-N) - Commercial source
2. triethylamine C6H15N (ZMANZCXQSJIPKH-UHFFFAOYSA-N) - Commercial source

Data

P = 100 kPa, T = 298.15 K
x (mol mol^-1)	H_m^E (kJ mol^-1)
0.1135	0.178
0.2162	0.336
0.3067	0.449
0.4077	0.534
0.5057	0.585
0.5750	0.596
0.7077	0.548
0.8027	0.448
0.8907	0.3

32861; pentan-2-one + triethylamine; 00828:01417