Modeling phase equilibria of ternary systems (water +  formic acid +  ester or alcohol) through UNIFAC-original, SERLAS, NRTL, NRTL-modified, and three-suffix Margules: Parameter estimation using genetic algorithm Senol, A.; Bilgin, M.; Baslioglu, B.; Vakili-Nezhaad, G.; Fluid Phase Equilibria 2016, 429, 254-265
Data
T = 298.2 K, P = 101.3 kPa
x (mol mol-1) x (mol mol-1) x (mol mol-1) x (mol mol-1)
0.9734 0.0 0.0001 0.0
0.2557 0.4445 0.0015 0.3613
0.2161 0.4592 0.0027 0.3956
0.8196 0.1379 0.0001 0.0666
0.7743 0.1711 0.0001 0.0954
0.6559 0.2159 0.0001 0.1371
0.5338 0.2729 0.0001 0.1779
0.5090 0.2913 0.0001 0.2047
0.4389 0.3197 0.0004 0.2398
0.3748 0.3842 0.0006 0.2822
0.3240 0.4106 0.0008 0.3091
35328; formic acid + diethyl decanedioate + water; 00004:00125:03259