Modeling phase equilibria of ternary systems (water +  formic acid +  ester or alcohol) through UNIFAC-original, SERLAS, NRTL, NRTL-modified, and three-suffix Margules: Parameter estimation using genetic algorithm Senol, A.; Bilgin, M.; Baslioglu, B.; Vakili-Nezhaad, G.; Fluid Phase Equilibria 2016, 429, 254-265
Data
T = 298.2 K, P = 101.3 kPa
x (mol mol-1) x (mol mol-1) x (mol mol-1) x (mol mol-1)
0.9077 0.0 0.0002 0.0
0.7114 0.0869 0.0027 0.0316
0.5866 0.1396 0.0037 0.0595
0.4560 0.199 0.0051 0.0912
0.3294 0.226 0.0076 0.1181
0.2489 0.2459 0.0111 0.1432
35329; formic acid + diethyl butanedioate + water; 00004:00125:00218