Modeling phase equilibria of ternary systems (water +  formic acid +  ester or alcohol) through UNIFAC-original, SERLAS, NRTL, NRTL-modified, and three-suffix Margules: Parameter estimation using genetic algorithm Senol, A.; Bilgin, M.; Baslioglu, B.; Vakili-Nezhaad, G.; Fluid Phase Equilibria 2016, 429, 254-265
Data
T = 298.2 K, P = 101.3 kPa
x (mol mol-1) x (mol mol-1) x (mol mol-1) x (mol mol-1)
0 0.6401 0.0045 0.0
0.0720 0.5436 0.0062 0.0339
0.0960 0.5064 0.0077 0.0713
0.1207 0.4756 0.0121 0.1317
0.1410 0.4318 0.0329 0.214
35014; formic acid + 3-methylbutan-1-ol + water; 00004:00125:00447