Thermochemical behavior of crown ethers in the mixtures of water with organic solvents. Part VIII. Hydrophobic hydration and preferential solvation of 1,4-dioxane in {(1−x)amide + xH2O} at T = 298.15 K Jóźwiak, M.; The Journal of Chemical Thermodynamics 2007, 39, 433-437
Data
x = 0 mol mol-1, T = 298.15 K, P = 101 kPa
xsolv (mol mol-1) Hmsol (kJ mol-1)
0 1.29
0.90 -4.6
0.92 -5.25
0.94 -6.05
0.96 -7.06
0.98 -8.35
1 -9.7
0.10 1.47
0.20 1.6
0.30 1.78
0.40 1.8
0.50 1.71
0.60 1.25
0.70 0.25
0.80 -1.49
37922; N-methylformamide + 1,4-dioxane + water; 00004:00122:00749