Thermochemical behavior of crown ethers in the mixtures of water with organic solvents. Part VIII. Hydrophobic hydration and preferential solvation of 1,4-dioxane in {(1−x)amide + xH2O} at T = 298.15 K Jóźwiak, M.; The Journal of Chemical Thermodynamics 2007, 39, 433-437
Data
x = 0 mol mol-1, T = 298.15 K, P = 101 kPa
xsolv (mol mol-1) Hmsol (kJ mol-1)
0 -2.01
0.90 -7.56
0.92 -7.98
0.94 -8.33
0.96 -8.71
0.98 -9.1
1 -9.7
0.10 -2.24
0.20 -2.44
0.30 -2.82
0.40 -3.32
0.50 -3.86
0.60 -4.55
0.70 -5.39
0.80 -6.33
28222; formamide + 1,4-dioxane + water; 00004:00110:00122