Thermochemical behavior of crown ethers in the mixtures of water with organic solvents. Part VIII. Hydrophobic hydration and preferential solvation of 1,4-dioxane in {(1−x)amide + xH2O} at T = 298.15 K Jóźwiak, M.; The Journal of Chemical Thermodynamics 2007, 39, 433-437
Data
x = 0 mol mol-1, T = 298.15 K, P = 101 kPa
xsolv (mol mol-1) Hmsol (kJ mol-1)
0 0.86
0.90 -2.21
0.92 -3.27
0.94 -4.69
0.96 -5.92
0.98 -7.5
1 -9.7
0.10 1.41
0.20 1.99
0.30 2.7
0.40 3.38
0.50 4.24
0.60 4.47
0.70 3.82
0.80 1.79
11743; N,N-dimethylformamide + dioxane + water; 00004:00088:00122