The heat capacities and thermodynamic functions of 4-methylbiphenyl and 4-tert-butylbiphenyl Varushchenko, R.; Efimova, A.; Druzhinina, A.; Tkachenko, E.; Nesterov, I.; Nesterova, T.; Verevkin, S.; The Journal of Chemical Thermodynamics 2010, 42, 1265-1272
- Journal: The Journal of Chemical Thermodynamics
- Sample Quantity(ies): Molar heat capacity at constant pressure
- Methodology: Vacuum adiabatic calorimetry
- Phase(s): Crystal 2
- Substances:
Data
| T (K) | Cp (J mol-1 K-1) |
| 8.42 | 3.6981 |
| 11.83 | 7.8122 |
| 73.27 | 74.214 |
| 74.32 | 74.625 |
| 75.37 | 75.509 |
| 76.42 | 75.536 |
| 77.47 | 76.162 |
| 78.51 | 77.533 |
| 78.80 | 78.322 |
| 79.56 | 77.918 |
| 80.60 | 79.105 |
| 81.65 | 79.669 |
| 12.21 | 8.2864 |
| 82.17 | 81.46 |
| 83.21 | 81.225 |
| 84.78 | 82.634 |
| 85.83 | 84.238 |
| 87.34 | 85.253 |
| 88.37 | 86.402 |
| 89.40 | 87.094 |
| 90.43 | 87.846 |
| 91.47 | 88.19 |
| 92.50 | 89.194 |
| 12.59 | 8.7218 |
| 93.53 | 89.617 |
| 94.55 | 90.587 |
| 95.58 | 91.129 |
| 96.61 | 92.304 |
| 97.64 | 93.826 |
| 98.66 | 92.613 |
| 99.69 | 94.229 |
| 100.72 | 95.146 |
| 101.74 | 95.128 |
| 102.77 | 95.551 |
| 12.96 | 9.1935 |
| 104.82 | 96.612 |
| 105.84 | 97.413 |
| 106.86 | 98.568 |
| 107.88 | 99.358 |
| 108.90 | 99.571 |
| 109.93 | 100.46 |
| 110.95 | 100.63 |
| 111.97 | 100.49 |
| 112.99 | 102.03 |
| 114.01 | 102.56 |
| 13.35 | 9.7603 |
| 115.02 | 103.36 |
| 116.04 | 104.67 |
| 117.06 | 104.77 |
| 118.08 | 104.33 |
| 119.10 | 105.95 |
| 120.12 | 106.87 |
| 121.14 | 106.67 |
| 122.15 | 107.47 |
| 123.17 | 108.38 |
| 124.18 | 108.38 |
| 13.72 | 10.44 |
| 125.20 | 108.94 |
| 126.21 | 110.22 |
| 127.23 | 110.82 |
| 128.23 | 111.43 |
| 129.25 | 111.0 |
| 130.26 | 112.24 |
| 131.27 | 113.68 |
| 132.28 | 113.17 |
| 133.29 | 114.17 |
| 134.30 | 115.39 |
| 14.09 | 10.741 |
| 135.31 | 115.98 |
| 136.32 | 115.79 |
| 137.33 | 115.95 |
| 138.33 | 116.76 |
| 139.34 | 118.07 |
| 140.34 | 119.05 |
| 141.35 | 119.04 |
| 142.35 | 119.96 |
| 143.36 | 120.0 |
| 144.35 | 120.48 |
| 14.46 | 11.372 |
| 145.36 | 120.67 |
| 146.36 | 122.0 |
| 147.36 | 122.17 |
| 148.36 | 124.22 |
| 149.36 | 124.87 |
| 150.36 | 125.07 |
| 151.36 | 125.72 |
| 153.66 | 127.07 |
| 154.92 | 127.26 |
| 155.92 | 127.72 |
| 14.83 | 11.812 |
| 156.91 | 128.68 |
| 157.91 | 129.05 |
| 158.90 | 129.98 |
| 159.89 | 130.91 |
| 162.88 | 133.43 |
| 163.87 | 132.72 |
| 164.87 | 133.55 |
| 165.85 | 133.77 |
| 166.84 | 134.91 |
| 167.83 | 135.89 |
| 15.20 | 12.217 |
| 169.79 | 137.42 |
| 170.78 | 137.22 |
| 171.76 | 137.79 |
| 172.74 | 138.45 |
| 173.73 | 139.11 |
| 174.71 | 140.53 |
| 175.69 | 140.7 |
| 176.68 | 141.47 |
| 177.66 | 142.43 |
| 178.64 | 143.15 |
| 8.70 | 3.9959 |
| 15.56 | 12.796 |
| 179.62 | 143.76 |
| 180.60 | 144.25 |
| 181.58 | 145.06 |
| 182.56 | 146.17 |
| 183.54 | 146.07 |
| 184.52 | 146.77 |
| 185.47 | 148.0 |
| 186.45 | 148.42 |
| 187.42 | 148.71 |
| 188.40 | 149.77 |
| 15.92 | 13.351 |
| 189.37 | 150.31 |
| 190.34 | 151.29 |
| 191.32 | 152.46 |
| 192.29 | 153.07 |
| 193.26 | 153.26 |
| 194.23 | 154.48 |
| 195.20 | 154.92 |
| 196.17 | 155.18 |
| 197.14 | 156.43 |
| 198.10 | 156.66 |
| 16.28 | 13.948 |
| 199.07 | 156.85 |
| 200.03 | 158.25 |
| 201.21 | 159.08 |
| 202.67 | 160.39 |
| 204.13 | 161.16 |
| 205.59 | 161.88 |
| 207.05 | 163.01 |
| 208.50 | 164.47 |
| 209.95 | 165.42 |
| 211.41 | 166.95 |
| 16.65 | 14.46 |
| 212.86 | 167.72 |
| 214.31 | 168.81 |
| 215.75 | 169.75 |
| 217.19 | 170.91 |
| 218.63 | 172.34 |
| 220.07 | 173.54 |
| 221.51 | 174.81 |
| 224.33 | 177.09 |
| 225.77 | 178.63 |
| 227.21 | 179.26 |
| 17.01 | 14.643 |
| 228.64 | 180.46 |
| 230.07 | 181.65 |
| 231.50 | 183.05 |
| 232.92 | 183.59 |
| 234.35 | 184.76 |
| 235.77 | 186.0 |
| 237.20 | 186.68 |
| 238.62 | 188.83 |
| 240.04 | 189.96 |
| 241.46 | 190.95 |
| 17.37 | 15.378 |
| 242.88 | 191.92 |
| 245.71 | 194.12 |
| 247.06 | 195.69 |
| 248.47 | 196.82 |
| 249.87 | 197.8 |
| 251.28 | 198.95 |
| 252.68 | 199.51 |
| 254.07 | 203.15 |
| 255.46 | 205.87 |
| 256.86 | 204.64 |
| 17.72 | 16.093 |
| 258.26 | 207.95 |
| 259.65 | 209.9 |
| 261.05 | 211.67 |
| 262.45 | 213.5 |
| 263.84 | 216.69 |
| 265.26 | 218.04 |
| 265.74 | 214.98 |
| 266.62 | 215.48 |
| 267.35 | 216.35 |
| 268.06 | 216.34 |
| 18.08 | 16.368 |
| 268.77 | 218.41 |
| 269.46 | 217.65 |
| 270.14 | 220.43 |
| 270.81 | 221.73 |
| 271.48 | 224.8 |
| 272.13 | 226.98 |
| 272.79 | 228.68 |
| 273.44 | 230.85 |
| 274.09 | 231.46 |
| 274.73 | 233.58 |
| 18.44 | 17.108 |
| 275.38 | 235.91 |
| 276.02 | 236.58 |
| 276.54 | 238.77 |
| 277.18 | 240.39 |
| 277.82 | 243.02 |
| 278.45 | 244.38 |
| 279.09 | 245.39 |
| 279.72 | 247.06 |
| 280.35 | 249.06 |
| 280.98 | 250.28 |
| 18.79 | 17.506 |
| 281.61 | 250.82 |
| 282.22 | 253.9 |
| 282.84 | 255.25 |
| 283.47 | 256.25 |
| 284.09 | 257.26 |
| 284.71 | 258.2 |
| 285.32 | 261.0 |
| 285.94 | 262.67 |
| 286.41 | 265.19 |
| 287.03 | 266.14 |
| 8.96 | 4.2437 |
| 19.88 | 19.128 |
| 287.64 | 267.86 |
| 288.24 | 270.21 |
| 289.45 | 271.63 |
| 290.05 | 274.89 |
| 290.65 | 278.67 |
| 291.25 | 281.37 |
| 291.85 | 283.3 |
| 292.44 | 287.63 |
| 293.04 | 291.45 |
| 293.63 | 298.7 |
| 20.58 | 20.286 |
| 294.21 | 301.08 |
| 294.80 | 306.74 |
| 295.38 | 315.73 |
| 295.81 | 323.56 |
| 296.38 | 356.89 |
| 296.78 | 604.38 |
| 21.36 | 21.322 |
| 22.14 | 22.381 |
| 22.91 | 23.601 |
| 23.69 | 24.614 |
| 24.46 | 25.757 |
| 25.23 | 26.802 |
| 26.00 | 27.575 |
| 26.76 | 28.856 |
| 9.47 | 4.8345 |
| 27.53 | 30.07 |
| 28.29 | 30.899 |
| 29.05 | 32.046 |
| 29.81 | 33.032 |
| 30.57 | 34.284 |
| 31.33 | 35.245 |
| 32.09 | 36.413 |
| 32.86 | 36.832 |
| 33.62 | 38.308 |
| 34.37 | 39.144 |
| 9.97 | 5.4325 |
| 35.13 | 39.928 |
| 35.88 | 41.046 |
| 36.64 | 41.535 |
| 37.39 | 42.341 |
| 38.14 | 43.779 |
| 38.90 | 44.06 |
| 39.65 | 45.398 |
| 40.40 | 45.986 |
| 41.15 | 46.639 |
| 41.90 | 47.815 |
| 10.28 | 5.7777 |
| 42.65 | 48.692 |
| 43.40 | 49.756 |
| 44.15 | 50.637 |
| 44.91 | 50.569 |
| 45.66 | 51.277 |
| 46.41 | 52.333 |
| 47.16 | 53.307 |
| 47.91 | 53.956 |
| 48.65 | 55.094 |
| 49.40 | 56.247 |
| 10.67 | 6.2733 |
| 50.15 | 56.825 |
| 50.90 | 57.261 |
| 51.65 | 58.125 |
| 52.40 | 59.372 |
| 53.15 | 59.895 |
| 53.90 | 60.724 |
| 54.64 | 61.656 |
| 55.39 | 62.703 |
| 56.14 | 63.644 |
| 56.89 | 63.485 |
| 11.06 | 6.7767 |
| 57.64 | 64.25 |
| 58.39 | 64.496 |
| 59.13 | 64.984 |
| 59.88 | 65.467 |
| 60.63 | 66.027 |
| 61.37 | 65.921 |
| 62.12 | 66.394 |
| 62.86 | 67.014 |
| 63.60 | 67.59 |
| 64.35 | 67.747 |
| 11.44 | 7.3385 |
| 65.09 | 68.237 |
| 65.83 | 68.992 |
| 66.57 | 69.458 |
| 67.32 | 69.911 |
| 68.06 | 70.285 |
| 68.80 | 70.753 |
| 69.54 | 72.078 |
| 70.28 | 72.225 |
| 71.18 | 72.289 |
| 72.22 | 73.132 |
32431; 4-methylbiphenyl; 00880