NIST TRC ThermoML Dataset

Volumetric properties and enthalpies of solution of alcohols CkH2k + 1OH (k = 1, 2, 6) in 1-methyl-3-alkylimidazolium bis(trifluoromethylsulfonyl)imide {[C1CnIm][NTf2] n = 2, 4, 6, 8, 10} ionic liquids Deng, Y.; Husson, P.; Jacquemin, J.; Youngs, T.; Kett, V.; Hardacre, C.; Costa Gomes, M.; The Journal of Chemical Thermodynamics 2011, 43, 1708-1718

Journal: The Journal of Chemical Thermodynamics
Sample Quantity(ies): Excess molar enthalpy
Methodology: Isothermal Titration Calorimeter
Phase(s): Liquid
Substances:
1. 1-hexanol C6H14O (ZSIAUFGUXNUGDI-UHFFFAOYSA-N) - Commercial source
2. 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide C8H11F6N3O4S2 (LRESCJAINPKJTO-UHFFFAOYSA-N) - Synthesized by the authors

Data

P = 101 kPa, T = 298.15 K
x (mol mol^-1)	H_m^E (kJ mol^-1)
0.0036	0.026
0.0072	0.049
0.0107	0.069
0.0142	0.086
0.0177	0.1
0.0212	0.111
0.0246	0.12

40001; hexan-1-ol + 1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide; 00045:00128