Phase equilibria and the thermodynamic properties of methyl and ethyl esters of carboxylic acids. 1. Methyl n-butanoate and ethyl propanoate Agafonova, L.E.; Varushchenko, R.M.; Druzhinina, A.I.; Polyakova, O.V.; The Journal of Chemical Thermodynamics 2012, 47, 120-129
- Journal: The Journal of Chemical Thermodynamics
- Sample Quantity(ies): Molar heat capacity at constant pressure
- Methodology: Vacuum adiabatic calorimetry
- Phase(s): Crystal
- Substances:
Data
| T (K) | Cp (J mol-1 K-1) |
| 7.61 | 1.24 |
| 9.91 | 2.719 |
| 68.72 | 67.726 |
| 69.46 | 68.236 |
| 70.20 | 68.471 |
| 71.09 | 68.752 |
| 72.14 | 69.62 |
| 73.19 | 70.474 |
| 74.24 | 70.878 |
| 75.29 | 71.508 |
| 76.34 | 72.301 |
| 77.39 | 72.874 |
| 10.22 | 2.8943 |
| 78.44 | 73.354 |
| 78.68 | 72.623 |
| 79.48 | 74.122 |
| 79.71 | 73.823 |
| 80.53 | 74.827 |
| 80.74 | 74.412 |
| 81.58 | 75.433 |
| 81.76 | 74.798 |
| 82.62 | 75.675 |
| 82.79 | 75.478 |
| 10.60 | 3.3004 |
| 83.67 | 76.361 |
| 83.81 | 75.483 |
| 84.83 | 76.857 |
| 85.85 | 77.507 |
| 86.87 | 77.781 |
| 87.89 | 78.68 |
| 88.91 | 79.57 |
| 89.93 | 79.992 |
| 90.96 | 80.423 |
| 91.97 | 80.848 |
| 10.98 | 3.648 |
| 92.99 | 81.427 |
| 94.01 | 82.017 |
| 95.03 | 82.389 |
| 96.04 | 83.434 |
| 97.06 | 84.19 |
| 98.07 | 84.163 |
| 99.09 | 84.885 |
| 100.10 | 85.448 |
| 101.62 | 86.177 |
| 103.64 | 87.3 |
| 11.35 | 4.0641 |
| 105.66 | 88.283 |
| 107.68 | 89.362 |
| 109.70 | 90.169 |
| 111.72 | 91.075 |
| 113.73 | 92.149 |
| 115.74 | 93.341 |
| 117.75 | 94.236 |
| 119.76 | 95.16 |
| 121.76 | 96.242 |
| 123.77 | 97.126 |
| 11.73 | 4.3799 |
| 125.78 | 98.021 |
| 127.78 | 98.841 |
| 129.79 | 99.75 |
| 131.79 | 100.55 |
| 133.79 | 101.43 |
| 135.80 | 102.27 |
| 137.80 | 103.03 |
| 139.79 | 103.9 |
| 141.79 | 104.89 |
| 143.79 | 105.51 |
| 12.13 | 4.7346 |
| 145.78 | 106.36 |
| 147.78 | 107.25 |
| 149.77 | 107.92 |
| 151.89 | 109.06 |
| 153.86 | 109.91 |
| 155.85 | 110.69 |
| 157.83 | 111.73 |
| 159.81 | 112.47 |
| 161.79 | 113.29 |
| 163.77 | 114.29 |
| 12.50 | 5.1107 |
| 165.74 | 115.26 |
| 167.72 | 116.18 |
| 169.56 | 116.65 |
| 171.52 | 117.81 |
| 173.49 | 119.09 |
| 175.45 | 120.75 |
| 177.41 | 122.58 |
| 179.36 | 125.17 |
| 181.29 | 129.69 |
| 183.20 | 139.88 |
| 12.86 | 5.563 |
| 185.04 | 158.37 |
| 186.78 | 216.75 |
| 188.21 | 448.34 |
| 189.16 | 1561.8 |
| 189.70 | 8659.7 |
| 191.08 | 185.22 |
| 13.23 | 5.9072 |
| 7.88 | 1.3814 |
| 13.60 | 6.2781 |
| 13.96 | 6.6465 |
| 14.33 | 7.0629 |
| 14.68 | 7.551 |
| 15.04 | 7.9198 |
| 15.40 | 8.3179 |
| 15.76 | 8.8246 |
| 16.11 | 9.3325 |
| 16.47 | 9.6521 |
| 16.82 | 10.207 |
| 8.13 | 1.5137 |
| 17.17 | 10.66 |
| 17.53 | 11.074 |
| 17.88 | 11.412 |
| 18.23 | 11.836 |
| 18.58 | 12.532 |
| 18.93 | 12.898 |
| 19.28 | 13.532 |
| 19.63 | 13.976 |
| 19.98 | 14.419 |
| 20.62 | 15.198 |
| 8.39 | 1.6567 |
| 21.39 | 16.16 |
| 22.15 | 17.23 |
| 22.91 | 18.291 |
| 23.67 | 19.351 |
| 24.44 | 20.586 |
| 25.20 | 21.608 |
| 25.97 | 22.55 |
| 26.73 | 23.641 |
| 27.49 | 24.493 |
| 28.25 | 25.817 |
| 8.65 | 1.8054 |
| 29.01 | 26.927 |
| 29.77 | 27.907 |
| 30.53 | 29.041 |
| 31.29 | 29.602 |
| 32.82 | 31.82 |
| 33.59 | 32.786 |
| 34.35 | 33.885 |
| 35.11 | 34.581 |
| 35.86 | 35.634 |
| 36.61 | 36.635 |
| 8.90 | 2.1076 |
| 37.37 | 37.49 |
| 38.12 | 38.325 |
| 38.88 | 38.881 |
| 39.63 | 39.871 |
| 40.39 | 40.689 |
| 41.14 | 41.428 |
| 41.90 | 42.115 |
| 42.65 | 43.213 |
| 43.40 | 43.996 |
| 44.16 | 44.506 |
| 9.16 | 2.2068 |
| 44.91 | 45.662 |
| 45.66 | 46.291 |
| 46.41 | 47.132 |
| 47.17 | 47.632 |
| 47.92 | 48.664 |
| 48.66 | 49.52 |
| 49.41 | 50.202 |
| 50.16 | 50.977 |
| 50.91 | 51.687 |
| 51.66 | 52.269 |
| 9.41 | 2.4659 |
| 52.40 | 53.157 |
| 53.15 | 54.062 |
| 53.89 | 54.63 |
| 54.64 | 55.703 |
| 55.38 | 56.476 |
| 56.12 | 57.162 |
| 56.87 | 57.901 |
| 59.09 | 60.079 |
| 59.84 | 60.446 |
| 60.58 | 61.417 |
| 9.66 | 2.5492 |
| 61.32 | 62.073 |
| 62.06 | 62.683 |
| 62.80 | 63.435 |
| 63.54 | 64.04 |
| 64.28 | 64.717 |
| 65.03 | 65.054 |
| 65.77 | 65.697 |
| 66.50 | 66.393 |
| 67.24 | 66.793 |
| 67.98 | 67.344 |
937; methyl butanoate; 00342